catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]

In the title polymer, [Mn(C(8)H(8)O(5))(H(2)O)(2)](n), the Mn(II) atom is in a distorted octa­hedral coordination mode, binding to the bridging O atom of the bicyclo­heptane unit, two O atoms from corresponding carboxyl­ate groups, one carboxyl­ate O atom from a symmetry-related bridging ligand and...

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Detalles Bibliográficos
Autores principales: Wang, Na, Feng, Jie, Wang, Dong-Hang, Lin, Qiu-Yue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979419/
https://www.ncbi.nlm.nih.gov/pubmed/21579348
http://dx.doi.org/10.1107/S1600536810019021
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author Wang, Na
Feng, Jie
Wang, Dong-Hang
Lin, Qiu-Yue
author_facet Wang, Na
Feng, Jie
Wang, Dong-Hang
Lin, Qiu-Yue
author_sort Wang, Na
collection PubMed
description In the title polymer, [Mn(C(8)H(8)O(5))(H(2)O)(2)](n), the Mn(II) atom is in a distorted octa­hedral coordination mode, binding to the bridging O atom of the bicyclo­heptane unit, two O atoms from corresponding carboxyl­ate groups, one carboxyl­ate O atom from a symmetry-related bridging ligand and two water O atoms. This arrangement leads to the formation of polymeric chains propagating parallel to [001]. The crystal structure is stabilized by several O—H⋯O hydrogen-bonding inter­actions involving the coordinated water mol­ecules as donors and the carboxyl­ate O atoms as acceptors.
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spelling pubmed-29794192010-12-30 catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato] Wang, Na Feng, Jie Wang, Dong-Hang Lin, Qiu-Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [Mn(C(8)H(8)O(5))(H(2)O)(2)](n), the Mn(II) atom is in a distorted octa­hedral coordination mode, binding to the bridging O atom of the bicyclo­heptane unit, two O atoms from corresponding carboxyl­ate groups, one carboxyl­ate O atom from a symmetry-related bridging ligand and two water O atoms. This arrangement leads to the formation of polymeric chains propagating parallel to [001]. The crystal structure is stabilized by several O—H⋯O hydrogen-bonding inter­actions involving the coordinated water mol­ecules as donors and the carboxyl­ate O atoms as acceptors. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979419/ /pubmed/21579348 http://dx.doi.org/10.1107/S1600536810019021 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Na
Feng, Jie
Wang, Dong-Hang
Lin, Qiu-Yue
catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_full catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_fullStr catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_full_unstemmed catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_short catena-Poly[[diaqua­manganese(II)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_sort catena-poly[[diaqua­manganese(ii)]-μ-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979419/
https://www.ncbi.nlm.nih.gov/pubmed/21579348
http://dx.doi.org/10.1107/S1600536810019021
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