Bis[3-dimethyl­amino-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (2′),O]tris­(nitrato-κ(2) O,O′)praseodymium(III)

In the title compound, [Pr(NO(3))(3)(C(10)H(12)N(2)O)(2)], the Pr(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one ligands and by six O atoms from three nitrate anions in a distorted bicapped square-anti­prismatic geometry. An e...

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Detalles Bibliográficos
Autor principal: Hu, Da-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979422/
https://www.ncbi.nlm.nih.gov/pubmed/21579342
http://dx.doi.org/10.1107/S1600536810018817
Descripción
Sumario:In the title compound, [Pr(NO(3))(3)(C(10)H(12)N(2)O)(2)], the Pr(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one ligands and by six O atoms from three nitrate anions in a distorted bicapped square-anti­prismatic geometry. An extensive three-dimensional network of weak inter­molecular C—H⋯O hydrogen bonds consolidates the crystal packing.

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