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Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2) N (2′),O]tris(nitrato-κ(2) O,O′)praseodymium(III)
In the title compound, [Pr(NO(3))(3)(C(10)H(12)N(2)O)(2)], the Pr(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(dimethylamino)-1-(2-pyridyl)prop-2-en-1-one ligands and by six O atoms from three nitrate anions in a distorted bicapped square-antiprismatic geometry. An e...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979422/ https://www.ncbi.nlm.nih.gov/pubmed/21579342 http://dx.doi.org/10.1107/S1600536810018817 |
| _version_ | 1782191408866656256 |
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| author | Hu, Da-Hua |
| author_facet | Hu, Da-Hua |
| author_sort | Hu, Da-Hua |
| collection | PubMed |
| description | In the title compound, [Pr(NO(3))(3)(C(10)H(12)N(2)O)(2)], the Pr(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(dimethylamino)-1-(2-pyridyl)prop-2-en-1-one ligands and by six O atoms from three nitrate anions in a distorted bicapped square-antiprismatic geometry. An extensive three-dimensional network of weak intermolecular C—H⋯O hydrogen bonds consolidates the crystal packing. |
| format | Text |
| id | pubmed-2979422 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29794222010-12-30 Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2) N (2′),O]tris(nitrato-κ(2) O,O′)praseodymium(III) Hu, Da-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pr(NO(3))(3)(C(10)H(12)N(2)O)(2)], the Pr(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(dimethylamino)-1-(2-pyridyl)prop-2-en-1-one ligands and by six O atoms from three nitrate anions in a distorted bicapped square-antiprismatic geometry. An extensive three-dimensional network of weak intermolecular C—H⋯O hydrogen bonds consolidates the crystal packing. International Union of Crystallography 2010-05-26 /pmc/articles/PMC2979422/ /pubmed/21579342 http://dx.doi.org/10.1107/S1600536810018817 Text en © Da-Hua Hu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hu, Da-Hua Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2) N (2′),O]tris(nitrato-κ(2) O,O′)praseodymium(III) |
| title | Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2)
N
(2′),O]tris(nitrato-κ(2)
O,O′)praseodymium(III) |
| title_full | Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2)
N
(2′),O]tris(nitrato-κ(2)
O,O′)praseodymium(III) |
| title_fullStr | Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2)
N
(2′),O]tris(nitrato-κ(2)
O,O′)praseodymium(III) |
| title_full_unstemmed | Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2)
N
(2′),O]tris(nitrato-κ(2)
O,O′)praseodymium(III) |
| title_short | Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2)
N
(2′),O]tris(nitrato-κ(2)
O,O′)praseodymium(III) |
| title_sort | bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ(2)
n
(2′),o]tris(nitrato-κ(2)
o,o′)praseodymium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979422/ https://www.ncbi.nlm.nih.gov/pubmed/21579342 http://dx.doi.org/10.1107/S1600536810018817 |
| work_keys_str_mv | AT hudahua bis3dimethylamino12pyridylprop2en1onek2n2otrisnitratok2oopraseodymiumiii |