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4,4′-Dimethyl-1,1′-(p-phenylenedimethylene)dipyridinium bis[7,7,8,8-tetracyanoquinodimethanide(1−)]
In the title salt, C(20)H(22)N(2) (2+)·2C(12)H(4)N(4) (−), the cations and anions stack along the b axis into segregated columns. In the cation, which has a crystallographically imposed centre of symmetry, the dihedral angle between the benzene and pyridine rings is 89.14 (4)°. Centrosymmetrically r...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979426/ https://www.ncbi.nlm.nih.gov/pubmed/21579443 http://dx.doi.org/10.1107/S1600536810017113 |
Sumario: | In the title salt, C(20)H(22)N(2) (2+)·2C(12)H(4)N(4) (−), the cations and anions stack along the b axis into segregated columns. In the cation, which has a crystallographically imposed centre of symmetry, the dihedral angle between the benzene and pyridine rings is 89.14 (4)°. Centrosymmetrically related anions form dimers by π–π stacking interactions, with centroid–centroid separations of 3.874 (4) Å. The crystal packing is stabilized by intercolumnar C—H⋯N hydrogen bonds. |
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