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4,4′-Dimethyl-1,1′-(p-phenyl­enedimethyl­ene)dipyridinium bis­[7,7,8,8-tetra­cyano­quinodimethanide(1−)]

In the title salt, C(20)H(22)N(2) (2+)·2C(12)H(4)N(4) (−), the cations and anions stack along the b axis into segregated columns. In the cation, which has a crystallographically imposed centre of symmetry, the dihedral angle between the benzene and pyridine rings is 89.14 (4)°. Centrosymmetrically r...

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Detalles Bibliográficos
Autor principal: Liu, Guang-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979426/
https://www.ncbi.nlm.nih.gov/pubmed/21579443
http://dx.doi.org/10.1107/S1600536810017113
Descripción
Sumario:In the title salt, C(20)H(22)N(2) (2+)·2C(12)H(4)N(4) (−), the cations and anions stack along the b axis into segregated columns. In the cation, which has a crystallographically imposed centre of symmetry, the dihedral angle between the benzene and pyridine rings is 89.14 (4)°. Centrosymmetrically related anions form dimers by π–π stacking inter­actions, with centroid–centroid separations of 3.874 (4) Å. The crystal packing is stabilized by inter­columnar C—H⋯N hydrogen bonds.