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[(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridylpyrimidin-2-yl)ethenolato]chlorido(N,N-dimethylformamide-κO)zinc(II)
In the title complex, [Zn(C(17)H(11)N(6)O)Cl(C(3)H(7)NO)], the Zn(II) atom has a distorted square-pyramidal coordination formed by one Cl, two O and two N atoms. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link molecules into centrosymmetric dimers, which are further assembled b...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979429/ https://www.ncbi.nlm.nih.gov/pubmed/21579320 http://dx.doi.org/10.1107/S1600536810017770 |
| Sumario: | In the title complex, [Zn(C(17)H(11)N(6)O)Cl(C(3)H(7)NO)], the Zn(II) atom has a distorted square-pyramidal coordination formed by one Cl, two O and two N atoms. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link molecules into centrosymmetric dimers, which are further assembled by π–π interactions [centroid–centroid distances = 3.809 (3) and 3.834 (3) Å] into layers parallel to the ab plane. The crystal packing exhibits also weak intermolecular C—H⋯Cl interactions. |
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