[(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II)

In the title complex, [Zn(C(17)H(11)N(6)O)Cl(C(3)H(7)NO)], the Zn(II) atom has a distorted square-pyramidal coordination formed by one Cl, two O and two N atoms. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link mol­ecules into centrosymmetric dimers, which are further assembled b...

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Detalles Bibliográficos
Autores principales: Jian, Fangfang, Du, Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979429/
https://www.ncbi.nlm.nih.gov/pubmed/21579320
http://dx.doi.org/10.1107/S1600536810017770
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author Jian, Fangfang
Du, Mei
author_facet Jian, Fangfang
Du, Mei
author_sort Jian, Fangfang
collection PubMed
description In the title complex, [Zn(C(17)H(11)N(6)O)Cl(C(3)H(7)NO)], the Zn(II) atom has a distorted square-pyramidal coordination formed by one Cl, two O and two N atoms. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link mol­ecules into centrosymmetric dimers, which are further assembled by π–π inter­actions [centroid–centroid distances = 3.809 (3) and 3.834 (3) Å] into layers parallel to the ab plane. The crystal packing exhibits also weak inter­molecular C—H⋯Cl inter­actions.
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spelling pubmed-29794292010-12-30 [(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II) Jian, Fangfang Du, Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(17)H(11)N(6)O)Cl(C(3)H(7)NO)], the Zn(II) atom has a distorted square-pyramidal coordination formed by one Cl, two O and two N atoms. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link mol­ecules into centrosymmetric dimers, which are further assembled by π–π inter­actions [centroid–centroid distances = 3.809 (3) and 3.834 (3) Å] into layers parallel to the ab plane. The crystal packing exhibits also weak inter­molecular C—H⋯Cl inter­actions. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979429/ /pubmed/21579320 http://dx.doi.org/10.1107/S1600536810017770 Text en © Jian and Du 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jian, Fangfang
Du, Mei
[(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II)
title [(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II)
title_full [(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II)
title_fullStr [(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II)
title_full_unstemmed [(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II)
title_short [(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl­formamide-κO)zinc(II)
title_sort [(z)-1-amino-2-cyano-2-(4,6-di-2-pyridyl­pyrimidin-2-yl)ethenolato]chlorido(n,n-dimethyl­formamide-κo)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979429/
https://www.ncbi.nlm.nih.gov/pubmed/21579320
http://dx.doi.org/10.1107/S1600536810017770
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AT dumei z1amino2cyano246di2pyridylpyrimidin2ylethenolatochloridonndimethylformamidekozincii

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