4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate

In the title compound, C(7)H(10)N(+)·BF(4) (−)·C(12)H(24)O(6), the proton­ated 4-methyl­anilinium cation inter­acts with 18-crown-6 forming a rotator–stator structure, (C(6)H(4)CH(3)NH(3) (+))(18-crown-6), through three bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium groups of the cations (...

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Detalles Bibliográficos
Autores principales: Ge, Jia-Zhen, Zhao, Min-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979430/
https://www.ncbi.nlm.nih.gov/pubmed/21579544
http://dx.doi.org/10.1107/S1600536810019033
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author Ge, Jia-Zhen
Zhao, Min-Min
author_facet Ge, Jia-Zhen
Zhao, Min-Min
author_sort Ge, Jia-Zhen
collection PubMed
description In the title compound, C(7)H(10)N(+)·BF(4) (−)·C(12)H(24)O(6), the proton­ated 4-methyl­anilinium cation inter­acts with 18-crown-6 forming a rotator–stator structure, (C(6)H(4)CH(3)NH(3) (+))(18-crown-6), through three bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium groups of the cations (–NH(3)) and the O atoms of the crown ether mol­ecule. The BF(4) (−) anions, the methyl group and the protonated –NH(3) groups of the 4-methylanilinium lie on a dual axis of rotation. The 18-crown-6 unit is perpendicular to the dual axis of rotation and the mirror plane which contains the dual axis of rotation. The benzene ring of 4-methylanilinium is perpendicular to the mirror plane and parallel to the dual axis.
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spelling pubmed-29794302010-12-30 4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate Ge, Jia-Zhen Zhao, Min-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(10)N(+)·BF(4) (−)·C(12)H(24)O(6), the proton­ated 4-methyl­anilinium cation inter­acts with 18-crown-6 forming a rotator–stator structure, (C(6)H(4)CH(3)NH(3) (+))(18-crown-6), through three bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium groups of the cations (–NH(3)) and the O atoms of the crown ether mol­ecule. The BF(4) (−) anions, the methyl group and the protonated –NH(3) groups of the 4-methylanilinium lie on a dual axis of rotation. The 18-crown-6 unit is perpendicular to the dual axis of rotation and the mirror plane which contains the dual axis of rotation. The benzene ring of 4-methylanilinium is perpendicular to the mirror plane and parallel to the dual axis. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979430/ /pubmed/21579544 http://dx.doi.org/10.1107/S1600536810019033 Text en © Ge and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ge, Jia-Zhen
Zhao, Min-Min
4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title 4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_full 4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_fullStr 4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_full_unstemmed 4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_short 4-Methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_sort 4-methyl­anilinium tetra­fluoro­borate 18-crown-6 clathrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979430/
https://www.ncbi.nlm.nih.gov/pubmed/21579544
http://dx.doi.org/10.1107/S1600536810019033
work_keys_str_mv AT gejiazhen 4methylaniliniumtetrafluoroborate18crown6clathrate
AT zhaominmin 4methylaniliniumtetrafluoroborate18crown6clathrate

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