(1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II)

In the title complex, [Mn(C(6)H(4)NO(2)S)(2)(C(12)H(8)N(2))] or [MnL (2)(phen)] (L = 2-mercaptonicotinate and phen = 1,10-phenanthroline), the central Mn(II) atom is coordinated by two carboxylic O atoms and two thiol­ate S atoms of two L ligands and two N atoms from one phen mol­ecule, giving a dis...

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Detalles Bibliográficos
Autor principal: Li, Wei-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979431/
https://www.ncbi.nlm.nih.gov/pubmed/21579295
http://dx.doi.org/10.1107/S160053681001514X
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author Li, Wei-Qi
author_facet Li, Wei-Qi
author_sort Li, Wei-Qi
collection PubMed
description In the title complex, [Mn(C(6)H(4)NO(2)S)(2)(C(12)H(8)N(2))] or [MnL (2)(phen)] (L = 2-mercaptonicotinate and phen = 1,10-phenanthroline), the central Mn(II) atom is coordinated by two carboxylic O atoms and two thiol­ate S atoms of two L ligands and two N atoms from one phen mol­ecule, giving a distorted octa­hedral geometry. The pyridyl H atoms form strong N—H⋯O hydrogen bonds with the carbonyl O atoms of the adjacent mol­ecules, generating a chain structure propagating in [100].
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spelling pubmed-29794312010-12-30 (1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II) Li, Wei-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(6)H(4)NO(2)S)(2)(C(12)H(8)N(2))] or [MnL (2)(phen)] (L = 2-mercaptonicotinate and phen = 1,10-phenanthroline), the central Mn(II) atom is coordinated by two carboxylic O atoms and two thiol­ate S atoms of two L ligands and two N atoms from one phen mol­ecule, giving a distorted octa­hedral geometry. The pyridyl H atoms form strong N—H⋯O hydrogen bonds with the carbonyl O atoms of the adjacent mol­ecules, generating a chain structure propagating in [100]. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979431/ /pubmed/21579295 http://dx.doi.org/10.1107/S160053681001514X Text en © Wei-Qi Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Wei-Qi
(1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II)
title (1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II)
title_full (1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II)
title_fullStr (1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II)
title_full_unstemmed (1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II)
title_short (1,10-Phenanthroline-κ(2) N,N′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) O,S)manganese(II)
title_sort (1,10-phenanthroline-κ(2) n,n′)bis­(2-thioxo-1,2-dihydro­pyridine-3-car­box­yl­ato-κ(2) o,s)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979431/
https://www.ncbi.nlm.nih.gov/pubmed/21579295
http://dx.doi.org/10.1107/S160053681001514X
work_keys_str_mv AT liweiqi 110phenanthrolinek2nnbis2thioxo12dihydropyridine3carboxylatok2osmanganeseii

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