[2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I)

The title compound, [Co(C(30)H(23)O(2)P(2))(C(3)H(9)P)(2)], was synthesized by the addition of a Co(PMe(3))(4) solution to (PPh(2)O)(2)C(6)H(4). The Co(I) atom displays a trigonal-bipyramidal geometry with the two P atoms of the ‘PCP’ pincer ligand and the P atom of one of the trimethyl phosphine li...

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Detalles Bibliográficos
Autores principales: Lian, Zhe, Xu, Guoqiang, Li, Xiaoyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979432/
https://www.ncbi.nlm.nih.gov/pubmed/21579289
http://dx.doi.org/10.1107/S160053681001634X
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author Lian, Zhe
Xu, Guoqiang
Li, Xiaoyan
author_facet Lian, Zhe
Xu, Guoqiang
Li, Xiaoyan
author_sort Lian, Zhe
collection PubMed
description The title compound, [Co(C(30)H(23)O(2)P(2))(C(3)H(9)P)(2)], was synthesized by the addition of a Co(PMe(3))(4) solution to (PPh(2)O)(2)C(6)H(4). The Co(I) atom displays a trigonal-bipyramidal geometry with the two P atoms of the ‘PCP’ pincer ligand and the P atom of one of the trimethyl phosphine ligands forming the basal plane, whereas the metalated C atom and the P atom of the second phospine ligand occupy the apical sites. The Co—C distance is 1.961 (2) Å and the C—Co—P angle is 171.96 (6)°.
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spelling pubmed-29794322010-12-30 [2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I) Lian, Zhe Xu, Guoqiang Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(30)H(23)O(2)P(2))(C(3)H(9)P)(2)], was synthesized by the addition of a Co(PMe(3))(4) solution to (PPh(2)O)(2)C(6)H(4). The Co(I) atom displays a trigonal-bipyramidal geometry with the two P atoms of the ‘PCP’ pincer ligand and the P atom of one of the trimethyl phosphine ligands forming the basal plane, whereas the metalated C atom and the P atom of the second phospine ligand occupy the apical sites. The Co—C distance is 1.961 (2) Å and the C—Co—P angle is 171.96 (6)°. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979432/ /pubmed/21579289 http://dx.doi.org/10.1107/S160053681001634X Text en © Lian et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lian, Zhe
Xu, Guoqiang
Li, Xiaoyan
[2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I)
title [2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I)
title_full [2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I)
title_fullStr [2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I)
title_full_unstemmed [2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I)
title_short [2,6-Bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(I)
title_sort [2,6-bis(diphenyl­phosphino­oxy)phen­yl]bis­(trimethyl­phosphine)cobalt(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979432/
https://www.ncbi.nlm.nih.gov/pubmed/21579289
http://dx.doi.org/10.1107/S160053681001634X
work_keys_str_mv AT lianzhe 26bisdiphenylphosphinooxyphenylbistrimethylphosphinecobalti
AT xuguoqiang 26bisdiphenylphosphinooxyphenylbistrimethylphosphinecobalti
AT lixiaoyan 26bisdiphenylphosphinooxyphenylbistrimethylphosphinecobalti

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