catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)]

In the title compound, [Cd(2)(C(6)H(8)O(4))(2)(C(16)H(20)N(4))(H(2)O)(4)](n), penta­gonal-bipyramidally coordinated Cd(II) ions are connected into {Cd(2)(2,2-dimethyl­succinate)(2)(H(2)O)(4)} centrosymmetric dimeric clusters. In turn, these clusters are linked by tethering 1,4-bis­(3-pyridylmeth­yl)...

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Detalles Bibliográficos
Autores principales: Pochodylo, Amy L., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979442/
https://www.ncbi.nlm.nih.gov/pubmed/21579341
http://dx.doi.org/10.1107/S1600536810018799
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author Pochodylo, Amy L.
LaDuca, Robert L.
author_facet Pochodylo, Amy L.
LaDuca, Robert L.
author_sort Pochodylo, Amy L.
collection PubMed
description In the title compound, [Cd(2)(C(6)H(8)O(4))(2)(C(16)H(20)N(4))(H(2)O)(4)](n), penta­gonal-bipyramidally coordinated Cd(II) ions are connected into {Cd(2)(2,2-dimethyl­succinate)(2)(H(2)O)(4)} centrosymmetric dimeric clusters. In turn, these clusters are linked by tethering 1,4-bis­(3-pyridylmeth­yl)piperazine (3-bpmp) ligands into [Cd(2)(2,2-dimethyl­succinate)(2)(3-bpmp)(H(2)O)(4)](n) coordination polymer chains. The chain motifs are oriented parallel to [1[Image: see text]0]. Individual chains are connected into supra­molecular layers via O—H⋯N and O—H⋯O hydrogen-bonding mechanisms.
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spelling pubmed-29794422010-12-30 catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)] Pochodylo, Amy L. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)(C(6)H(8)O(4))(2)(C(16)H(20)N(4))(H(2)O)(4)](n), penta­gonal-bipyramidally coordinated Cd(II) ions are connected into {Cd(2)(2,2-dimethyl­succinate)(2)(H(2)O)(4)} centrosymmetric dimeric clusters. In turn, these clusters are linked by tethering 1,4-bis­(3-pyridylmeth­yl)piperazine (3-bpmp) ligands into [Cd(2)(2,2-dimethyl­succinate)(2)(3-bpmp)(H(2)O)(4)](n) coordination polymer chains. The chain motifs are oriented parallel to [1[Image: see text]0]. Individual chains are connected into supra­molecular layers via O—H⋯N and O—H⋯O hydrogen-bonding mechanisms. International Union of Crystallography 2010-05-26 /pmc/articles/PMC2979442/ /pubmed/21579341 http://dx.doi.org/10.1107/S1600536810018799 Text en © Pochodylo and LaDuca 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pochodylo, Amy L.
LaDuca, Robert L.
catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)]
title catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)]
title_full catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)]
title_fullStr catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)]
title_full_unstemmed catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)]
title_short catena-Poly[[diaqua­cadmium(II)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) O,O′:O′′,O′′′)[diaqua­cadmium(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N (3):N (3′)]
title_sort catena-poly[[diaqua­cadmium(ii)]bis­(μ-2,2-dimethyl­butane­dioato-κ(4) o,o′:o′′,o′′′)[diaqua­cadmium(ii)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) n (3):n (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979442/
https://www.ncbi.nlm.nih.gov/pubmed/21579341
http://dx.doi.org/10.1107/S1600536810018799
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AT laducarobertl catenapolydiaquacadmiumiibism22dimethylbutanedioatok4oooodiaquacadmiumiim14bis3pyridylmethylpiperazinek2n3n3

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