N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide

In the title compound, C(14)H(14)ClNO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −54.9 (2)°. The sulfonyl and aniline benzene rings are rotated relative...

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979443/
https://www.ncbi.nlm.nih.gov/pubmed/21579381
http://dx.doi.org/10.1107/S1600536810015916
_version_ 1782191413888286720
author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, C(14)H(14)ClNO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −54.9 (2)°. The sulfonyl and aniline benzene rings are rotated relative to each other by 75.7 (1)°. An intra­molecular N—H⋯Cl hydrogen bond is present. In the crystal, inter­molecular N—H⋯O hydrogen-bonding inter­actions are observed and the mol­ecules are packed into chains parallel to the b axis.
format Text
id pubmed-2979443
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29794432010-12-30 N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)ClNO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −54.9 (2)°. The sulfonyl and aniline benzene rings are rotated relative to each other by 75.7 (1)°. An intra­molecular N—H⋯Cl hydrogen bond is present. In the crystal, inter­molecular N—H⋯O hydrogen-bonding inter­actions are observed and the mol­ecules are packed into chains parallel to the b axis. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979443/ /pubmed/21579381 http://dx.doi.org/10.1107/S1600536810015916 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_full N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_fullStr N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_full_unstemmed N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_short N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_sort n-(2-chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979443/
https://www.ncbi.nlm.nih.gov/pubmed/21579381
http://dx.doi.org/10.1107/S1600536810015916
work_keys_str_mv AT gowdabthimme n2chlorophenyl24dimethylbenzenesulfonamide
AT forosabine n2chlorophenyl24dimethylbenzenesulfonamide
AT nirmalapg n2chlorophenyl24dimethylbenzenesulfonamide
AT fuesshartmut n2chlorophenyl24dimethylbenzenesulfonamide

Ejemplares similares