Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)

In the title complex, [W(C(3)H(6)N(2)S)(CO)(5)], the W atom displays an octa­hedral coordination with five CO mol­ecules and an imidazolidine-2-thione mol­ecule. The W(CO)(5) unit is coordinated by the cyclic thione ligand through a W—S dative bond. The W—S and C—S bond lengths are 2.599 (2) and 1.7...

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Autores principales: Merniz, Salah, Mokhtari, Mahiedine, Mousser, Hénia, Ouahab, Lahcène, Mousser, Abdelhamid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979448/
https://www.ncbi.nlm.nih.gov/pubmed/21579284
http://dx.doi.org/10.1107/S1600536810016314
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author Merniz, Salah
Mokhtari, Mahiedine
Mousser, Hénia
Ouahab, Lahcène
Mousser, Abdelhamid
author_facet Merniz, Salah
Mokhtari, Mahiedine
Mousser, Hénia
Ouahab, Lahcène
Mousser, Abdelhamid
author_sort Merniz, Salah
collection PubMed
description In the title complex, [W(C(3)H(6)N(2)S)(CO)(5)], the W atom displays an octa­hedral coordination with five CO mol­ecules and an imidazolidine-2-thione mol­ecule. The W(CO)(5) unit is coordinated by the cyclic thione ligand through a W—S dative bond. The W—S and C—S bond lengths are 2.599 (2) and 1.711 (9) Å, respectively. This last distance is significantly longer than that of free cyclic thio­ureas. The geometry of the title compound suggests sp (3)-hybridization of the S atom caused by the greatly polarized linkage W—S—C bond angle, which is close to tetra­hedral [109.50 (3)°]. In the crystal packing, N—H⋯O and N—H⋯S hydrogen-bonding inter­actions stabilize the structure and build up chains parallel to [101].
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spelling pubmed-29794482010-12-30 Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0) Merniz, Salah Mokhtari, Mahiedine Mousser, Hénia Ouahab, Lahcène Mousser, Abdelhamid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [W(C(3)H(6)N(2)S)(CO)(5)], the W atom displays an octa­hedral coordination with five CO mol­ecules and an imidazolidine-2-thione mol­ecule. The W(CO)(5) unit is coordinated by the cyclic thione ligand through a W—S dative bond. The W—S and C—S bond lengths are 2.599 (2) and 1.711 (9) Å, respectively. This last distance is significantly longer than that of free cyclic thio­ureas. The geometry of the title compound suggests sp (3)-hybridization of the S atom caused by the greatly polarized linkage W—S—C bond angle, which is close to tetra­hedral [109.50 (3)°]. In the crystal packing, N—H⋯O and N—H⋯S hydrogen-bonding inter­actions stabilize the structure and build up chains parallel to [101]. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979448/ /pubmed/21579284 http://dx.doi.org/10.1107/S1600536810016314 Text en © Merniz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Merniz, Salah
Mokhtari, Mahiedine
Mousser, Hénia
Ouahab, Lahcène
Mousser, Abdelhamid
Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)
title Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)
title_full Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)
title_fullStr Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)
title_full_unstemmed Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)
title_short Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)
title_sort penta­carbon­yl(imidazolidine-2-thione-κs)tungsten(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979448/
https://www.ncbi.nlm.nih.gov/pubmed/21579284
http://dx.doi.org/10.1107/S1600536810016314
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AT mousserhenia pentacarbonylimidazolidine2thionekstungsten0
AT ouahablahcene pentacarbonylimidazolidine2thionekstungsten0
AT mousserabdelhamid pentacarbonylimidazolidine2thionekstungsten0

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