1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione

In the title compound, C(16)H(12)Cl(2)O(3), the benzene rings form a dihedral angle of 2.0 (3)°. Within the central O=C—CH(2)C(H)OH—C=O unit, the carbonyl groups are coplanar and lie to opposite sides [O—C⋯C—O = −170.1 (6)°]. In the crystal, inter­molecular O—H⋯O hydrogen bonds formed between the hy...

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Detalles Bibliográficos
Autores principales: Liu, Yongjun, Yang, Kuiwei, Song, Weiling, Qi, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979451/
https://www.ncbi.nlm.nih.gov/pubmed/21579502
http://dx.doi.org/10.1107/S1600536810018027
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author Liu, Yongjun
Yang, Kuiwei
Song, Weiling
Qi, Yan
author_facet Liu, Yongjun
Yang, Kuiwei
Song, Weiling
Qi, Yan
author_sort Liu, Yongjun
collection PubMed
description In the title compound, C(16)H(12)Cl(2)O(3), the benzene rings form a dihedral angle of 2.0 (3)°. Within the central O=C—CH(2)C(H)OH—C=O unit, the carbonyl groups are coplanar and lie to opposite sides [O—C⋯C—O = −170.1 (6)°]. In the crystal, inter­molecular O—H⋯O hydrogen bonds formed between the hydr­oxy groups lead to a supra­molecular chain along the c axis. In addition, the crystal packing features some very weak C—H⋯π inter­actions.
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spelling pubmed-29794512010-12-30 1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione Liu, Yongjun Yang, Kuiwei Song, Weiling Qi, Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(12)Cl(2)O(3), the benzene rings form a dihedral angle of 2.0 (3)°. Within the central O=C—CH(2)C(H)OH—C=O unit, the carbonyl groups are coplanar and lie to opposite sides [O—C⋯C—O = −170.1 (6)°]. In the crystal, inter­molecular O—H⋯O hydrogen bonds formed between the hydr­oxy groups lead to a supra­molecular chain along the c axis. In addition, the crystal packing features some very weak C—H⋯π inter­actions. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979451/ /pubmed/21579502 http://dx.doi.org/10.1107/S1600536810018027 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Yongjun
Yang, Kuiwei
Song, Weiling
Qi, Yan
1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione
title 1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione
title_full 1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione
title_fullStr 1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione
title_full_unstemmed 1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione
title_short 1,4-Bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione
title_sort 1,4-bis(4-chloro­phen­yl)-2-hydroxy­butane-1,4-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979451/
https://www.ncbi.nlm.nih.gov/pubmed/21579502
http://dx.doi.org/10.1107/S1600536810018027
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AT yangkuiwei 14bis4chlorophenyl2hydroxybutane14dione
AT songweiling 14bis4chlorophenyl2hydroxybutane14dione
AT qiyan 14bis4chlorophenyl2hydroxybutane14dione

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