[2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II)

The Pd(II) atom in the title compound, [Pd(C(2)F(3)O(2))(C(24)H(43)P(2))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intra­molecular C—H⋯O hydrogen bonds occur. The crystal packing reveals one weak inter­molecular...

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Detalles Bibliográficos
Autores principales: Johnson, Magnus T., Cetina, Mario, Rissanen, Kari, Wendt, Ola F.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979456/
https://www.ncbi.nlm.nih.gov/pubmed/21579315
http://dx.doi.org/10.1107/S1600536810017861
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author Johnson, Magnus T.
Cetina, Mario
Rissanen, Kari
Wendt, Ola F.
author_facet Johnson, Magnus T.
Cetina, Mario
Rissanen, Kari
Wendt, Ola F.
author_sort Johnson, Magnus T.
collection PubMed
description The Pd(II) atom in the title compound, [Pd(C(2)F(3)O(2))(C(24)H(43)P(2))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intra­molecular C—H⋯O hydrogen bonds occur. The crystal packing reveals one weak inter­molecular C—H⋯O hydrogen bond, which self-assembles the mol­ecules into infinite chains parallel to the b axis.
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spelling pubmed-29794562010-12-30 [2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II) Johnson, Magnus T. Cetina, Mario Rissanen, Kari Wendt, Ola F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) atom in the title compound, [Pd(C(2)F(3)O(2))(C(24)H(43)P(2))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intra­molecular C—H⋯O hydrogen bonds occur. The crystal packing reveals one weak inter­molecular C—H⋯O hydrogen bond, which self-assembles the mol­ecules into infinite chains parallel to the b axis. International Union of Crystallography 2010-05-19 /pmc/articles/PMC2979456/ /pubmed/21579315 http://dx.doi.org/10.1107/S1600536810017861 Text en © Johnson et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Johnson, Magnus T.
Cetina, Mario
Rissanen, Kari
Wendt, Ola F.
[2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II)
title [2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II)
title_full [2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II)
title_fullStr [2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II)
title_full_unstemmed [2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II)
title_short [2,6-Bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) P,C (1),P′](trifluoro­acetato)palladium(II)
title_sort [2,6-bis(di-tert-butyl­phosphinometh­yl)phenyl-κ(3) p,c (1),p′](trifluoro­acetato)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979456/
https://www.ncbi.nlm.nih.gov/pubmed/21579315
http://dx.doi.org/10.1107/S1600536810017861
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