Cargando…
Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate
In the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(13)H(9)O(2))(2)·2.66H(2)O, the Cu(II) centre (located at an inversion centre) is coordinated by two bidentate ethylenediamine (en) ligands and two water O atoms in a typical Jahn–Teller distorted octahedral geometry. The amino groups and the w...
Autores principales: | , , , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979460/ https://www.ncbi.nlm.nih.gov/pubmed/21579282 http://dx.doi.org/10.1107/S1600536810016223 |
_version_ | 1782191418057424896 |
---|---|
author | Fernandes, José A. Ramos, Ana I. Silva, Patrícia Braga, Susana S. Ribeiro-Claro, Paulo Rocha, João Almeida Paz, Filipe A. |
author_facet | Fernandes, José A. Ramos, Ana I. Silva, Patrícia Braga, Susana S. Ribeiro-Claro, Paulo Rocha, João Almeida Paz, Filipe A. |
author_sort | Fernandes, José A. |
collection | PubMed |
description | In the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(13)H(9)O(2))(2)·2.66H(2)O, the Cu(II) centre (located at an inversion centre) is coordinated by two bidentate ethylenediamine (en) ligands and two water O atoms in a typical Jahn–Teller distorted octahedral geometry. The amino groups and the water molecules are disordered over two distinct crystallographic positions with occupancies of 1/3 and 2/3. In the crystal, the cations and anions are disposed in alternating layers. One of the water molecules of crystallization is disordered and the other has a fractional occupation. In the 2/3 occupancy component, water molecules are organized into a chain composed of hexameric units interconnected by carboxylate bridges. |
format | Text |
id | pubmed-2979460 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29794602010-12-30 Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate Fernandes, José A. Ramos, Ana I. Silva, Patrícia Braga, Susana S. Ribeiro-Claro, Paulo Rocha, João Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(13)H(9)O(2))(2)·2.66H(2)O, the Cu(II) centre (located at an inversion centre) is coordinated by two bidentate ethylenediamine (en) ligands and two water O atoms in a typical Jahn–Teller distorted octahedral geometry. The amino groups and the water molecules are disordered over two distinct crystallographic positions with occupancies of 1/3 and 2/3. In the crystal, the cations and anions are disposed in alternating layers. One of the water molecules of crystallization is disordered and the other has a fractional occupation. In the 2/3 occupancy component, water molecules are organized into a chain composed of hexameric units interconnected by carboxylate bridges. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979460/ /pubmed/21579282 http://dx.doi.org/10.1107/S1600536810016223 Text en © Fernandes et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fernandes, José A. Ramos, Ana I. Silva, Patrícia Braga, Susana S. Ribeiro-Claro, Paulo Rocha, João Almeida Paz, Filipe A. Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
title | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
title_full | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
title_fullStr | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
title_full_unstemmed | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
title_short | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate |
title_sort | diaquabis(ethylenediamine-κ(2)
n,n′)copper(ii) bis(4-phenylbenzoate) 2.66-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979460/ https://www.ncbi.nlm.nih.gov/pubmed/21579282 http://dx.doi.org/10.1107/S1600536810016223 |
work_keys_str_mv | AT fernandesjosea diaquabisethylenediaminek2nncopperiibis4phenylbenzoate266hydrate AT ramosanai diaquabisethylenediaminek2nncopperiibis4phenylbenzoate266hydrate AT silvapatricia diaquabisethylenediaminek2nncopperiibis4phenylbenzoate266hydrate AT bragasusanas diaquabisethylenediaminek2nncopperiibis4phenylbenzoate266hydrate AT ribeiroclaropaulo diaquabisethylenediaminek2nncopperiibis4phenylbenzoate266hydrate AT rochajoao diaquabisethylenediaminek2nncopperiibis4phenylbenzoate266hydrate AT almeidapazfilipea diaquabisethylenediaminek2nncopperiibis4phenylbenzoate266hydrate |