Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)]

The title compound, [Ag(2)(NO(3))(2)(C(28)H(30)N(2)P(2))](n), crystallizes in polymeric α-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless hel...

Descripción completa

Detalles Bibliográficos
Autores principales: Kriel, Frederik H., Fernandes, Manuel A., Coates, Judy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979462/
https://www.ncbi.nlm.nih.gov/pubmed/21579343
http://dx.doi.org/10.1107/S1600536810019094
_version_ 1782191418522992640
author Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
author_facet Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
author_sort Kriel, Frederik H.
collection PubMed
description The title compound, [Ag(2)(NO(3))(2)(C(28)H(30)N(2)P(2))](n), crystallizes in polymeric α-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless helical chains that run along the c axis. The crystal used for the data collection was a racemic twin.
format Text
id pubmed-2979462
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29794622010-12-30 Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)] Kriel, Frederik H. Fernandes, Manuel A. Coates, Judy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(2)(NO(3))(2)(C(28)H(30)N(2)P(2))](n), crystallizes in polymeric α-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless helical chains that run along the c axis. The crystal used for the data collection was a racemic twin. International Union of Crystallography 2010-05-26 /pmc/articles/PMC2979462/ /pubmed/21579343 http://dx.doi.org/10.1107/S1600536810019094 Text en © Kriel et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)]
title Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)]
title_full Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)]
title_fullStr Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)]
title_full_unstemmed Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)]
title_short Poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)]
title_sort poly[[μ(2)-1,2-bis­(diphenyl­phosphan­yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979462/
https://www.ncbi.nlm.nih.gov/pubmed/21579343
http://dx.doi.org/10.1107/S1600536810019094
work_keys_str_mv AT krielfrederikh polym212bisdiphenylphosphanyl12diethylhydrazinem4nitratom2nitratosilveri
AT fernandesmanuela polym212bisdiphenylphosphanyl12diethylhydrazinem4nitratom2nitratosilveri
AT coatesjudy polym212bisdiphenylphosphanyl12diethylhydrazinem4nitratom2nitratosilveri

Ejemplares similares