Cargando…

2-Amino-5-methyl­pyridinium 2-carb­oxy­acetate

In the title mol­ecular salt, C(6)H(9)N(2) (+)·C(3)H(3)O(4) (−), the cation is essentially planar, with a maximum deviation of 0.010 (3) Å. In the anion, an intra­molecular O—H⋯O hydrogen bond generates an S(6) ring and results in a folded conformation. In the crystal, the protonated NH group and th...

Descripción completa

Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979470/
https://www.ncbi.nlm.nih.gov/pubmed/21579546
http://dx.doi.org/10.1107/S1600536810019239
Descripción
Sumario:In the title mol­ecular salt, C(6)H(9)N(2) (+)·C(3)H(3)O(4) (−), the cation is essentially planar, with a maximum deviation of 0.010 (3) Å. In the anion, an intra­molecular O—H⋯O hydrogen bond generates an S(6) ring and results in a folded conformation. In the crystal, the protonated NH group and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. Weak inter­molecular C—H⋯O inter­actions help to further stabilize the crystal structure.