[N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium

In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra­hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy­ethane mol­ec...

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Detalles Bibliográficos
Autores principales: Grubba, Rafał, Ponikiewski, Łukasz, Tomorowicz, Łukasz, Pikies, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979477/
https://www.ncbi.nlm.nih.gov/pubmed/21579340
http://dx.doi.org/10.1107/S1600536810018222
Descripción
Sumario:In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra­hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy­ethane mol­ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å.

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