[N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium

In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra­hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy­ethane mol­ec...

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Autores principales: Grubba, Rafał, Ponikiewski, Łukasz, Tomorowicz, Łukasz, Pikies, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979477/
https://www.ncbi.nlm.nih.gov/pubmed/21579340
http://dx.doi.org/10.1107/S1600536810018222
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author Grubba, Rafał
Ponikiewski, Łukasz
Tomorowicz, Łukasz
Pikies, Jerzy
author_facet Grubba, Rafał
Ponikiewski, Łukasz
Tomorowicz, Łukasz
Pikies, Jerzy
author_sort Grubba, Rafał
collection PubMed
description In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra­hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy­ethane mol­ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å.
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spelling pubmed-29794772010-12-30 [N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium Grubba, Rafał Ponikiewski, Łukasz Tomorowicz, Łukasz Pikies, Jerzy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra­hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy­ethane mol­ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å. International Union of Crystallography 2010-05-26 /pmc/articles/PMC2979477/ /pubmed/21579340 http://dx.doi.org/10.1107/S1600536810018222 Text en © Grubba et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Grubba, Rafał
Ponikiewski, Łukasz
Tomorowicz, Łukasz
Pikies, Jerzy
[N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium
title [N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium
title_full [N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium
title_fullStr [N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium
title_full_unstemmed [N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium
title_short [N,N′-Bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) N,N′]-μ(2)-chlorido-1:2κ(2) Cl:Cl-chlorido-2κCl-bis­(1,2-di­methoxy­ethane-1κ(2) O,O′)iron(II)lithium
title_sort [n,n′-bis(2,6-diisopropyl­phen­yl)pentane-2,4-diamine­(1–)-2κ(2) n,n′]-μ(2)-chlorido-1:2κ(2) cl:cl-chlorido-2κcl-bis­(1,2-di­methoxy­ethane-1κ(2) o,o′)iron(ii)lithium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979477/
https://www.ncbi.nlm.nih.gov/pubmed/21579340
http://dx.doi.org/10.1107/S1600536810018222
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AT pikiesjerzy nnbis26diisopropylphenylpentane24diamine12k2nnm2chlorido12k2clclchlorido2kclbis12dimethoxyethane1k2ooironiilithium

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