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[1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)

In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio­amide S atom from the tridentate thio­semicarbazonate dianion, and the N atom o...

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Detalles Bibliográficos
Autores principales: Bon, Vladimir V., Orysyk, Svitlana I., Pekhnyo, Vasily I.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979479/
https://www.ncbi.nlm.nih.gov/pubmed/21579316
http://dx.doi.org/10.1107/S1600536810017381
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author Bon, Vladimir V.
Orysyk, Svitlana I.
Pekhnyo, Vasily I.
author_facet Bon, Vladimir V.
Orysyk, Svitlana I.
Pekhnyo, Vasily I.
author_sort Bon, Vladimir V.
collection PubMed
description In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio­amide S atom from the tridentate thio­semicarbazonate dianion, and the N atom of a pyridine mol­ecule. The thio­semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N—H⋯S, C—H⋯O, C—H⋯N and C—H⋯S hydrogen-bonding inter­actions consolidates the structure.
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spelling pubmed-29794792010-12-30 [1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II) Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio­amide S atom from the tridentate thio­semicarbazonate dianion, and the N atom of a pyridine mol­ecule. The thio­semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N—H⋯S, C—H⋯O, C—H⋯N and C—H⋯S hydrogen-bonding inter­actions consolidates the structure. International Union of Crystallography 2010-05-19 /pmc/articles/PMC2979479/ /pubmed/21579316 http://dx.doi.org/10.1107/S1600536810017381 Text en © Bon et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bon, Vladimir V.
Orysyk, Svitlana I.
Pekhnyo, Vasily I.
[1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)
title [1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)
title_full [1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)
title_fullStr [1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)
title_full_unstemmed [1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)
title_short [1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)
title_sort [1-(2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ(3) o,n (1),s](pyridine-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979479/
https://www.ncbi.nlm.nih.gov/pubmed/21579316
http://dx.doi.org/10.1107/S1600536810017381
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