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[1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II)
In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thioamide S atom from the tridentate thiosemicarbazonate dianion, and the N atom o...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979479/ https://www.ncbi.nlm.nih.gov/pubmed/21579316 http://dx.doi.org/10.1107/S1600536810017381 |
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author | Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. |
author_facet | Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. |
author_sort | Bon, Vladimir V. |
collection | PubMed |
description | In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thioamide S atom from the tridentate thiosemicarbazonate dianion, and the N atom of a pyridine molecule. The thiosemicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N—H⋯S, C—H⋯O, C—H⋯N and C—H⋯S hydrogen-bonding interactions consolidates the structure. |
format | Text |
id | pubmed-2979479 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29794792010-12-30 [1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II) Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thioamide S atom from the tridentate thiosemicarbazonate dianion, and the N atom of a pyridine molecule. The thiosemicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N—H⋯S, C—H⋯O, C—H⋯N and C—H⋯S hydrogen-bonding interactions consolidates the structure. International Union of Crystallography 2010-05-19 /pmc/articles/PMC2979479/ /pubmed/21579316 http://dx.doi.org/10.1107/S1600536810017381 Text en © Bon et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bon, Vladimir V. Orysyk, Svitlana I. Pekhnyo, Vasily I. [1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3) O,N (1),S](pyridine-κN)copper(II) |
title | [1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3)
O,N
(1),S](pyridine-κN)copper(II) |
title_full | [1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3)
O,N
(1),S](pyridine-κN)copper(II) |
title_fullStr | [1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3)
O,N
(1),S](pyridine-κN)copper(II) |
title_full_unstemmed | [1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3)
O,N
(1),S](pyridine-κN)copper(II) |
title_short | [1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3)
O,N
(1),S](pyridine-κN)copper(II) |
title_sort | [1-(2-oxidobenzylidene)-4-phenylthiosemicarbazidato-κ(3)
o,n
(1),s](pyridine-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979479/ https://www.ncbi.nlm.nih.gov/pubmed/21579316 http://dx.doi.org/10.1107/S1600536810017381 |
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