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2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione
In the title compound, C(32)H(30)N(2)O(7), the piperidone ring adopts a chair conformation and the five-membered ring of the dihydroindenone ring system adopts an envelope conformation. Intramolecular O—H⋯N and C—H⋯O hydrogen bonds occur. The dihedral angle between the two hydroxy-subsituted meth...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979481/ https://www.ncbi.nlm.nih.gov/pubmed/21579453 http://dx.doi.org/10.1107/S1600536810017216 |
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| author | Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Hemamalini, Madhukar Fun, Hoong-Kun |
| author_facet | Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Hemamalini, Madhukar Fun, Hoong-Kun |
| author_sort | Kumar, Raju Suresh |
| collection | PubMed |
| description | In the title compound, C(32)H(30)N(2)O(7), the piperidone ring adopts a chair conformation and the five-membered ring of the dihydroindenone ring system adopts an envelope conformation. Intramolecular O—H⋯N and C—H⋯O hydrogen bonds occur. The dihedral angle between the two hydroxy-subsituted methoxyphenyl rings is 71.12 (5)°. In the crystal structure, molecules are connected by intermolecular O—H⋯O hydrogen bonds, forming layers parallel to (001). These layers are further connected by C—H⋯O hydrogen bonds, forming a three-dimensional network. |
| format | Text |
| id | pubmed-2979481 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29794812010-12-30 2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(30)N(2)O(7), the piperidone ring adopts a chair conformation and the five-membered ring of the dihydroindenone ring system adopts an envelope conformation. Intramolecular O—H⋯N and C—H⋯O hydrogen bonds occur. The dihedral angle between the two hydroxy-subsituted methoxyphenyl rings is 71.12 (5)°. In the crystal structure, molecules are connected by intermolecular O—H⋯O hydrogen bonds, forming layers parallel to (001). These layers are further connected by C—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979481/ /pubmed/21579453 http://dx.doi.org/10.1107/S1600536810017216 Text en © Kumar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Hemamalini, Madhukar Fun, Hoong-Kun 2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione |
| title | 2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione |
| title_full | 2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione |
| title_fullStr | 2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione |
| title_full_unstemmed | 2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione |
| title_short | 2-Hydroxy-16-[(E)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione |
| title_sort | 2-hydroxy-16-[(e)-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0(2,10).0(3,8).0(10,14)]octadeca-3(8),4,6-triene-9,15-dione |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979481/ https://www.ncbi.nlm.nih.gov/pubmed/21579453 http://dx.doi.org/10.1107/S1600536810017216 |
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