1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide

In the title mol­ecule, C(8)H(9)N(3)O(3)S, the thio­semicarbazide =N—NH—C(=S)—NH— fragment is twist a different degree of twist in the three independent mol­ecules [dihedral angles = 7.6 (1), 11.6 (1) and 20.7 (1)°]. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. In the crystal, the hydr­oxy...

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Detalles Bibliográficos
Autores principales: Shawish, Hana Bashir, Maah, M. Jamil, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979487/
https://www.ncbi.nlm.nih.gov/pubmed/21579378
http://dx.doi.org/10.1107/S1600536810015850
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author Shawish, Hana Bashir
Maah, M. Jamil
Ng, Seik Weng
author_facet Shawish, Hana Bashir
Maah, M. Jamil
Ng, Seik Weng
author_sort Shawish, Hana Bashir
collection PubMed
description In the title mol­ecule, C(8)H(9)N(3)O(3)S, the thio­semicarbazide =N—NH—C(=S)—NH— fragment is twist a different degree of twist in the three independent mol­ecules [dihedral angles = 7.6 (1), 11.6 (1) and 20.7 (1)°]. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. In the crystal, the hydr­oxy and amino groups are hydrogen-bond donors and the O—H⋯O, O—H⋯S and N—H⋯O hydrogen bonds generate a layer motif.
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spelling pubmed-29794872010-12-30 1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide Shawish, Hana Bashir Maah, M. Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(8)H(9)N(3)O(3)S, the thio­semicarbazide =N—NH—C(=S)—NH— fragment is twist a different degree of twist in the three independent mol­ecules [dihedral angles = 7.6 (1), 11.6 (1) and 20.7 (1)°]. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. In the crystal, the hydr­oxy and amino groups are hydrogen-bond donors and the O—H⋯O, O—H⋯S and N—H⋯O hydrogen bonds generate a layer motif. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979487/ /pubmed/21579378 http://dx.doi.org/10.1107/S1600536810015850 Text en © Shawish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shawish, Hana Bashir
Maah, M. Jamil
Ng, Seik Weng
1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide
title 1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide
title_full 1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide
title_fullStr 1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide
title_full_unstemmed 1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide
title_short 1-(2,3,4-Trihydroxy­benzyl­idene)thio­semicarbazide
title_sort 1-(2,3,4-trihydroxy­benzyl­idene)thio­semicarbazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979487/
https://www.ncbi.nlm.nih.gov/pubmed/21579378
http://dx.doi.org/10.1107/S1600536810015850
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AT maahmjamil 1234trihydroxybenzylidenethiosemicarbazide
AT ngseikweng 1234trihydroxybenzylidenethiosemicarbazide

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