[μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)}

Each gold atom in the binuclear title compound, [Au(2)(C(9)H(9)N(2)O(3)S)(2)(C(25)H(22)P(2))], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P angles = 172.77 (6) and 173.84 (6)°], with the distortion due in part to a close intra­molecular Au⋯O contac...

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Detalles Bibliográficos
Autores principales: Ho, Soo Yei, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979488/
https://www.ncbi.nlm.nih.gov/pubmed/21579280
http://dx.doi.org/10.1107/S1600536810016326
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author Ho, Soo Yei
Tiekink, Edward R. T.
author_facet Ho, Soo Yei
Tiekink, Edward R. T.
author_sort Ho, Soo Yei
collection PubMed
description Each gold atom in the binuclear title compound, [Au(2)(C(9)H(9)N(2)O(3)S)(2)(C(25)H(22)P(2))], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P angles = 172.77 (6) and 173.84 (6)°], with the distortion due in part to a close intra­molecular Au⋯O contact [2.968 (11) and 2.963 (4) Å]. The mol­ecule adopts a U-shaped conformation allowing for the formation of an aurophilic Au⋯Au inter­action [3.2320 (5) Å]. Mol­ecules are consolidated in the crystal structure by C—H⋯π inter­actions. Disorder was noted for one of the eth­oxy groups with two orientations being resolved in a 0.679 (16):0.321 (16) ratio.
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spelling pubmed-29794882010-12-30 [μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)} Ho, Soo Yei Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Each gold atom in the binuclear title compound, [Au(2)(C(9)H(9)N(2)O(3)S)(2)(C(25)H(22)P(2))], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P angles = 172.77 (6) and 173.84 (6)°], with the distortion due in part to a close intra­molecular Au⋯O contact [2.968 (11) and 2.963 (4) Å]. The mol­ecule adopts a U-shaped conformation allowing for the formation of an aurophilic Au⋯Au inter­action [3.2320 (5) Å]. Mol­ecules are consolidated in the crystal structure by C—H⋯π inter­actions. Disorder was noted for one of the eth­oxy groups with two orientations being resolved in a 0.679 (16):0.321 (16) ratio. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979488/ /pubmed/21579280 http://dx.doi.org/10.1107/S1600536810016326 Text en © Ho and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ho, Soo Yei
Tiekink, Edward R. T.
[μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)}
title [μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)}
title_full [μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)}
title_fullStr [μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)}
title_full_unstemmed [μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)}
title_short [μ-1,2-Bis(diphenyl­phosphino)methane-κ(2) P:P′]bis­{[(Z)-O-ethyl N-(4-nitro­phen­yl)thio­carbamato-κS]gold(I)}
title_sort [μ-1,2-bis(diphenyl­phosphino)methane-κ(2) p:p′]bis­{[(z)-o-ethyl n-(4-nitro­phen­yl)thio­carbamato-κs]gold(i)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979488/
https://www.ncbi.nlm.nih.gov/pubmed/21579280
http://dx.doi.org/10.1107/S1600536810016326
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AT tiekinkedwardrt m12bisdiphenylphosphinomethanek2ppbiszoethyln4nitrophenylthiocarbamatoksgoldi

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