Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate

In the title compound, C(32)H(33)NO(6)S, the indole ring system makes dihedral angles of 62.78 (10) and 80.53 (8)°, respectively, with the phenyl and benzene rings. In the crystal, the mol­ecules are linked through inter­molecular C—H⋯O hydrogen bonds, forming a chain along the a axis. Between the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Saravanan, B., Dhayalan, V., Mohanakrishnan, A. K., Chakkaravarthi, G., Manivannan, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979489/
https://www.ncbi.nlm.nih.gov/pubmed/21579568
http://dx.doi.org/10.1107/S1600536810019690
_version_ 1782191425071349760
author Saravanan, B.
Dhayalan, V.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Manivannan, V.
author_facet Saravanan, B.
Dhayalan, V.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Manivannan, V.
author_sort Saravanan, B.
collection PubMed
description In the title compound, C(32)H(33)NO(6)S, the indole ring system makes dihedral angles of 62.78 (10) and 80.53 (8)°, respectively, with the phenyl and benzene rings. In the crystal, the mol­ecules are linked through inter­molecular C—H⋯O hydrogen bonds, forming a chain along the a axis. Between the chains, a weak aromatic π–π stacking inter­action [centroid–centroid distance = 3.831 (2) Å] is observed.
format Text
id pubmed-2979489
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29794892010-12-30 Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate Saravanan, B. Dhayalan, V. Mohanakrishnan, A. K. Chakkaravarthi, G. Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(33)NO(6)S, the indole ring system makes dihedral angles of 62.78 (10) and 80.53 (8)°, respectively, with the phenyl and benzene rings. In the crystal, the mol­ecules are linked through inter­molecular C—H⋯O hydrogen bonds, forming a chain along the a axis. Between the chains, a weak aromatic π–π stacking inter­action [centroid–centroid distance = 3.831 (2) Å] is observed. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979489/ /pubmed/21579568 http://dx.doi.org/10.1107/S1600536810019690 Text en © Saravanan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saravanan, B.
Dhayalan, V.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Manivannan, V.
Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate
title Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate
title_full Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate
title_fullStr Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate
title_full_unstemmed Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate
title_short Diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1H-indol-2-yl]methyl­idene}propane­dioate
title_sort diethyl 2-{[3-(2,4,6-trimethyl­benz­yl)-1-phenyl­sulfonyl-1h-indol-2-yl]methyl­idene}propane­dioate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979489/
https://www.ncbi.nlm.nih.gov/pubmed/21579568
http://dx.doi.org/10.1107/S1600536810019690
work_keys_str_mv AT saravananb diethyl23246trimethylbenzyl1phenylsulfonyl1hindol2ylmethylidenepropanedioate
AT dhayalanv diethyl23246trimethylbenzyl1phenylsulfonyl1hindol2ylmethylidenepropanedioate
AT mohanakrishnanak diethyl23246trimethylbenzyl1phenylsulfonyl1hindol2ylmethylidenepropanedioate
AT chakkaravarthig diethyl23246trimethylbenzyl1phenylsulfonyl1hindol2ylmethylidenepropanedioate
AT manivannanv diethyl23246trimethylbenzyl1phenylsulfonyl1hindol2ylmethylidenepropanedioate

Ejemplares similares