Cyclo­hexa­none 2-nitro­phenyl­hydrazone

In the title Schiff base compound, C(12)H(15)N(3)O(2), obtained from a condensation reaction of cyclo­hexa­none and 2-nitro­phenyl­hydrazine, the phenyl­hydrazone group is planar, the largest deviation from the mean plane being 0.0252 (12) Å, and the nitro fragment is twisted slightly with respect t...

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Detalles Bibliográficos
Autores principales: Yang, Bao-he, Niu, Jun-long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979490/
https://www.ncbi.nlm.nih.gov/pubmed/21579397
http://dx.doi.org/10.1107/S1600536810016156
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author Yang, Bao-he
Niu, Jun-long
author_facet Yang, Bao-he
Niu, Jun-long
author_sort Yang, Bao-he
collection PubMed
description In the title Schiff base compound, C(12)H(15)N(3)O(2), obtained from a condensation reaction of cyclo­hexa­none and 2-nitro­phenyl­hydrazine, the phenyl­hydrazone group is planar, the largest deviation from the mean plane being 0.0252 (12) Å, and the nitro fragment is twisted slightly with respect to the mean plane, making a dihedral angle of 6.96 (17)°. The cyclo­heaxanone ring displays a chair conformation. An intra­molecular N—H⋯O hydrogen bond helps to stabilize the mol­ecular structure.
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spelling pubmed-29794902010-12-30 Cyclo­hexa­none 2-nitro­phenyl­hydrazone Yang, Bao-he Niu, Jun-long Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base compound, C(12)H(15)N(3)O(2), obtained from a condensation reaction of cyclo­hexa­none and 2-nitro­phenyl­hydrazine, the phenyl­hydrazone group is planar, the largest deviation from the mean plane being 0.0252 (12) Å, and the nitro fragment is twisted slightly with respect to the mean plane, making a dihedral angle of 6.96 (17)°. The cyclo­heaxanone ring displays a chair conformation. An intra­molecular N—H⋯O hydrogen bond helps to stabilize the mol­ecular structure. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979490/ /pubmed/21579397 http://dx.doi.org/10.1107/S1600536810016156 Text en © Yang and Niu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Bao-he
Niu, Jun-long
Cyclo­hexa­none 2-nitro­phenyl­hydrazone
title Cyclo­hexa­none 2-nitro­phenyl­hydrazone
title_full Cyclo­hexa­none 2-nitro­phenyl­hydrazone
title_fullStr Cyclo­hexa­none 2-nitro­phenyl­hydrazone
title_full_unstemmed Cyclo­hexa­none 2-nitro­phenyl­hydrazone
title_short Cyclo­hexa­none 2-nitro­phenyl­hydrazone
title_sort cyclo­hexa­none 2-nitro­phenyl­hydrazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979490/
https://www.ncbi.nlm.nih.gov/pubmed/21579397
http://dx.doi.org/10.1107/S1600536810016156
work_keys_str_mv AT yangbaohe cyclohexanone2nitrophenylhydrazone
AT niujunlong cyclohexanone2nitrophenylhydrazone

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