Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]]

The title compound, {(C(8)H(20)N(2))[PbBr(4)]}(n), crystallizes as an inorganic–organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr(6) octa­hedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr(6) octa­hedra a...

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Detalles Bibliográficos
Autores principales: Rayner, Matthew Kyle, Billing, David Gordon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979491/
https://www.ncbi.nlm.nih.gov/pubmed/21579303
http://dx.doi.org/10.1107/S1600536810016806
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author Rayner, Matthew Kyle
Billing, David Gordon
author_facet Rayner, Matthew Kyle
Billing, David Gordon
author_sort Rayner, Matthew Kyle
collection PubMed
description The title compound, {(C(8)H(20)N(2))[PbBr(4)]}(n), crystallizes as an inorganic–organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr(6) octa­hedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr(6) octa­hedra and the organic cation exhibit [Image: see text] symmetry. The cations inter­act via N—H⋯Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.
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spelling pubmed-29794912010-12-30 Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]] Rayner, Matthew Kyle Billing, David Gordon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(8)H(20)N(2))[PbBr(4)]}(n), crystallizes as an inorganic–organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr(6) octa­hedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr(6) octa­hedra and the organic cation exhibit [Image: see text] symmetry. The cations inter­act via N—H⋯Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979491/ /pubmed/21579303 http://dx.doi.org/10.1107/S1600536810016806 Text en © Rayner and Billing 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rayner, Matthew Kyle
Billing, David Gordon
Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]]
title Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]]
title_full Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]]
title_fullStr Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]]
title_full_unstemmed Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]]
title_short Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(II)]]
title_sort poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-bromido-dibromido­plumbate(ii)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979491/
https://www.ncbi.nlm.nih.gov/pubmed/21579303
http://dx.doi.org/10.1107/S1600536810016806
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