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Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate)
In the title compound, [Tb(CH(3)CN)(C(23)H(26)O(8))(H(2)O)(3)](ClO(4))(3), the Tb(3+) atom is eight-coordinated by one N atom of an acetonitrile molecule, three water O atoms and four ligand O atoms. The Tb(3+) atom is located on one side of the macrocycle and the carbonyl oxygen coordinated to the...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979501/ https://www.ncbi.nlm.nih.gov/pubmed/21579338 http://dx.doi.org/10.1107/S1600536810018313 |
| _version_ | 1782191427964370944 |
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| author | He, Wen-Jie Pan, Xiao-Bo Yao, Li-Hui Yu, Bing-Ran Wu, Jin-Cai Tang, Ning |
| author_facet | He, Wen-Jie Pan, Xiao-Bo Yao, Li-Hui Yu, Bing-Ran Wu, Jin-Cai Tang, Ning |
| author_sort | He, Wen-Jie |
| collection | PubMed |
| description | In the title compound, [Tb(CH(3)CN)(C(23)H(26)O(8))(H(2)O)(3)](ClO(4))(3), the Tb(3+) atom is eight-coordinated by one N atom of an acetonitrile molecule, three water O atoms and four ligand O atoms. The Tb(3+) atom is located on one side of the macrocycle and the carbonyl oxygen coordinated to the terbium [Tb1—O1= 2.210 (3) Å] is bent out of the xanthone plane by 0.514 (3) Å. The geometry around terbium is a distorted two-capped trigonal prism. |
| format | Text |
| id | pubmed-2979501 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29795012010-12-30 Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate) He, Wen-Jie Pan, Xiao-Bo Yao, Li-Hui Yu, Bing-Ran Wu, Jin-Cai Tang, Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Tb(CH(3)CN)(C(23)H(26)O(8))(H(2)O)(3)](ClO(4))(3), the Tb(3+) atom is eight-coordinated by one N atom of an acetonitrile molecule, three water O atoms and four ligand O atoms. The Tb(3+) atom is located on one side of the macrocycle and the carbonyl oxygen coordinated to the terbium [Tb1—O1= 2.210 (3) Å] is bent out of the xanthone plane by 0.514 (3) Å. The geometry around terbium is a distorted two-capped trigonal prism. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979501/ /pubmed/21579338 http://dx.doi.org/10.1107/S1600536810018313 Text en © He et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers He, Wen-Jie Pan, Xiao-Bo Yao, Li-Hui Yu, Bing-Ran Wu, Jin-Cai Tang, Ning Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate) |
| title | Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate) |
| title_full | Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate) |
| title_fullStr | Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate) |
| title_full_unstemmed | Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate) |
| title_short | Acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9H-xanthen-9-one]terbium(III) tris(perchlorate) |
| title_sort | acetonitriletriaqua[3-ethoxy-1,8-(3,6,9-trioxaundecane-1,11-diyldioxy)-9h-xanthen-9-one]terbium(iii) tris(perchlorate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979501/ https://www.ncbi.nlm.nih.gov/pubmed/21579338 http://dx.doi.org/10.1107/S1600536810018313 |
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