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4-Methoxy­benzene­carbothio­amide

The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent mol­ecules with the meth­oxy groups oriented in opposite conformations. The mean planes of the carbothio­amide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the...

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Detalles Bibliográficos
Autores principales: Ali, Saqib, Hameed, Shahid, Luqman, Ahmad, Akhtar, Tashfeen, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979506/
https://www.ncbi.nlm.nih.gov/pubmed/21579373
http://dx.doi.org/10.1107/S1600536810015825
Descripción
Sumario:The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent mol­ecules with the meth­oxy groups oriented in opposite conformations. The mean planes of the carbothio­amide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the mol­ecules form dimers via intermolecular N—H⋯S inter­molecular hydrogen bonds, resulting in eight-membered rings of R (2) (2)(8) graph-set motif. The dimers are further linked by C—H⋯O hydrogen bonds into chains along the c axis. Adjacent chains inter­act through inter­molecular N—H⋯S hydrogen bonds, generating eight-membered rings of R (4) (2)(8) graph-set motif.