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4-Methoxybenzenecarbothioamide
The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent molecules with the methoxy groups oriented in opposite conformations. The mean planes of the carbothioamide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979506/ https://www.ncbi.nlm.nih.gov/pubmed/21579373 http://dx.doi.org/10.1107/S1600536810015825 |
Sumario: | The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent molecules with the methoxy groups oriented in opposite conformations. The mean planes of the carbothioamide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the molecules form dimers via intermolecular N—H⋯S intermolecular hydrogen bonds, resulting in eight-membered rings of R (2) (2)(8) graph-set motif. The dimers are further linked by C—H⋯O hydrogen bonds into chains along the c axis. Adjacent chains interact through intermolecular N—H⋯S hydrogen bonds, generating eight-membered rings of R (4) (2)(8) graph-set motif. |
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