4-Methoxy­benzene­carbothio­amide

The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent mol­ecules with the meth­oxy groups oriented in opposite conformations. The mean planes of the carbothio­amide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the...

Descripción completa

Detalles Bibliográficos
Autores principales: Ali, Saqib, Hameed, Shahid, Luqman, Ahmad, Akhtar, Tashfeen, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979506/
https://www.ncbi.nlm.nih.gov/pubmed/21579373
http://dx.doi.org/10.1107/S1600536810015825
_version_ 1782191429196447744
author Ali, Saqib
Hameed, Shahid
Luqman, Ahmad
Akhtar, Tashfeen
Parvez, Masood
author_facet Ali, Saqib
Hameed, Shahid
Luqman, Ahmad
Akhtar, Tashfeen
Parvez, Masood
author_sort Ali, Saqib
collection PubMed
description The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent mol­ecules with the meth­oxy groups oriented in opposite conformations. The mean planes of the carbothio­amide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the mol­ecules form dimers via intermolecular N—H⋯S inter­molecular hydrogen bonds, resulting in eight-membered rings of R (2) (2)(8) graph-set motif. The dimers are further linked by C—H⋯O hydrogen bonds into chains along the c axis. Adjacent chains inter­act through inter­molecular N—H⋯S hydrogen bonds, generating eight-membered rings of R (4) (2)(8) graph-set motif.
format Text
id pubmed-2979506
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29795062010-12-30 4-Methoxy­benzene­carbothio­amide Ali, Saqib Hameed, Shahid Luqman, Ahmad Akhtar, Tashfeen Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent mol­ecules with the meth­oxy groups oriented in opposite conformations. The mean planes of the carbothio­amide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the mol­ecules form dimers via intermolecular N—H⋯S inter­molecular hydrogen bonds, resulting in eight-membered rings of R (2) (2)(8) graph-set motif. The dimers are further linked by C—H⋯O hydrogen bonds into chains along the c axis. Adjacent chains inter­act through inter­molecular N—H⋯S hydrogen bonds, generating eight-membered rings of R (4) (2)(8) graph-set motif. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979506/ /pubmed/21579373 http://dx.doi.org/10.1107/S1600536810015825 Text en © Ali et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, Saqib
Hameed, Shahid
Luqman, Ahmad
Akhtar, Tashfeen
Parvez, Masood
4-Methoxy­benzene­carbothio­amide
title 4-Methoxy­benzene­carbothio­amide
title_full 4-Methoxy­benzene­carbothio­amide
title_fullStr 4-Methoxy­benzene­carbothio­amide
title_full_unstemmed 4-Methoxy­benzene­carbothio­amide
title_short 4-Methoxy­benzene­carbothio­amide
title_sort 4-methoxy­benzene­carbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979506/
https://www.ncbi.nlm.nih.gov/pubmed/21579373
http://dx.doi.org/10.1107/S1600536810015825
work_keys_str_mv AT alisaqib 4methoxybenzenecarbothioamide
AT hameedshahid 4methoxybenzenecarbothioamide
AT luqmanahmad 4methoxybenzenecarbothioamide
AT akhtartashfeen 4methoxybenzenecarbothioamide
AT parvezmasood 4methoxybenzenecarbothioamide

Ejemplares similares