(2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide

The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 Å) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) Å]. The conformation about the C=N double bond [1.268 (3) Å] is E. An intra­molecular N—H⋯N hydrogen bond occurs. Linear supra­mole...

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Detalles Bibliográficos
Autores principales: Garden, Simon J., Pinto, Angelo C., da Cunha, Fernanda R., Fontes, Silvia P., Lima, A. S., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979508/
https://www.ncbi.nlm.nih.gov/pubmed/21579511
http://dx.doi.org/10.1107/S1600536810018623
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author Garden, Simon J.
Pinto, Angelo C.
da Cunha, Fernanda R.
Fontes, Silvia P.
Lima, A. S.
Tiekink, Edward R. T.
author_facet Garden, Simon J.
Pinto, Angelo C.
da Cunha, Fernanda R.
Fontes, Silvia P.
Lima, A. S.
Tiekink, Edward R. T.
author_sort Garden, Simon J.
collection PubMed
description The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 Å) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) Å]. The conformation about the C=N double bond [1.268 (3) Å] is E. An intra­molecular N—H⋯N hydrogen bond occurs. Linear supra­molecular chains along the b axis mediated by O—H⋯O hydrogen-bonding inter­actions feature in the crystal structure. These chains are also stabilized by weak C—H⋯N contacts.
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spelling pubmed-29795082010-12-30 (2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide Garden, Simon J. Pinto, Angelo C. da Cunha, Fernanda R. Fontes, Silvia P. Lima, A. S. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 Å) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) Å]. The conformation about the C=N double bond [1.268 (3) Å] is E. An intra­molecular N—H⋯N hydrogen bond occurs. Linear supra­molecular chains along the b axis mediated by O—H⋯O hydrogen-bonding inter­actions feature in the crystal structure. These chains are also stabilized by weak C—H⋯N contacts. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979508/ /pubmed/21579511 http://dx.doi.org/10.1107/S1600536810018623 Text en © Garden et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Garden, Simon J.
Pinto, Angelo C.
da Cunha, Fernanda R.
Fontes, Silvia P.
Lima, A. S.
Tiekink, Edward R. T.
(2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide
title (2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide
title_full (2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide
title_fullStr (2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide
title_full_unstemmed (2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide
title_short (2E)-N-(3,5-Dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide
title_sort (2e)-n-(3,5-dibromo-4-methoxy­phen­yl)-2-(hydroxy­imino)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979508/
https://www.ncbi.nlm.nih.gov/pubmed/21579511
http://dx.doi.org/10.1107/S1600536810018623
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