{4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate

The asymmetric unit of the title compound, [PtCl(C(32)H(24)N(5))](ClO(4))(2)·2CH(3)CN·1.5H(2)O, comprises two unique Pt(II) complex cations, four perchlorate anions, four acetonitrile solvent mol­ecules and three water mol­ecules. The Pt atom is four-coordinated by a tridentate chelating 2,2′:6′,2′′...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Guiju, Li, Quan, Fu, Wenfu, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979511/
https://www.ncbi.nlm.nih.gov/pubmed/21579321
http://dx.doi.org/10.1107/S1600536810017782
_version_ 1782191430370852864
author Zhang, Guiju
Li, Quan
Fu, Wenfu
Wang, Daqi
author_facet Zhang, Guiju
Li, Quan
Fu, Wenfu
Wang, Daqi
author_sort Zhang, Guiju
collection PubMed
description The asymmetric unit of the title compound, [PtCl(C(32)H(24)N(5))](ClO(4))(2)·2CH(3)CN·1.5H(2)O, comprises two unique Pt(II) complex cations, four perchlorate anions, four acetonitrile solvent mol­ecules and three water mol­ecules. The Pt atom is four-coordinated by a tridentate chelating 2,2′:6′,2′′-terpyridine ligand and a chloride ion in a square-planar geometry with modest distortion imposed by the constraint of the terpyridyl ligand. The r.m.s. deviations from the plane comprising the four ligand donor atoms and the Pt atom are 0.0381 and 0.0472 Å in the two complex cations.
format Text
id pubmed-2979511
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29795112010-12-30 {4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate Zhang, Guiju Li, Quan Fu, Wenfu Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [PtCl(C(32)H(24)N(5))](ClO(4))(2)·2CH(3)CN·1.5H(2)O, comprises two unique Pt(II) complex cations, four perchlorate anions, four acetonitrile solvent mol­ecules and three water mol­ecules. The Pt atom is four-coordinated by a tridentate chelating 2,2′:6′,2′′-terpyridine ligand and a chloride ion in a square-planar geometry with modest distortion imposed by the constraint of the terpyridyl ligand. The r.m.s. deviations from the plane comprising the four ligand donor atoms and the Pt atom are 0.0381 and 0.0472 Å in the two complex cations. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979511/ /pubmed/21579321 http://dx.doi.org/10.1107/S1600536810017782 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Guiju
Li, Quan
Fu, Wenfu
Wang, Daqi
{4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate
title {4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate
title_full {4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate
title_fullStr {4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate
title_full_unstemmed {4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate
title_short {4′-[4-(4,4′-Bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(II) bis­(perchlorate) acetonitrile disolvate sesquihydrate
title_sort {4′-[4-(4,4′-bipyridin-1-ylmeth­yl)phen­yl]-2,2′:6′,2′′-terpyridine}chloridoplatinum(ii) bis­(perchlorate) acetonitrile disolvate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979511/
https://www.ncbi.nlm.nih.gov/pubmed/21579321
http://dx.doi.org/10.1107/S1600536810017782
work_keys_str_mv AT zhangguiju 4444bipyridin1ylmethylphenyl2262terpyridinechloridoplatinumiibisperchlorateacetonitriledisolvatesesquihydrate
AT liquan 4444bipyridin1ylmethylphenyl2262terpyridinechloridoplatinumiibisperchlorateacetonitriledisolvatesesquihydrate
AT fuwenfu 4444bipyridin1ylmethylphenyl2262terpyridinechloridoplatinumiibisperchlorateacetonitriledisolvatesesquihydrate
AT wangdaqi 4444bipyridin1ylmethylphenyl2262terpyridinechloridoplatinumiibisperchlorateacetonitriledisolvatesesquihydrate

Ejemplares similares