4-Methyl­benzene­carbothio­amide

In the title mol­ecule, C(8)H(9)NS, the mean plane of the carbothio­amide group is twisted slightly with respect to the mean plane of the benzene ring, making a dihedral angle of 17.03 (10)°. The crystal structure is stabilized by inter­molecular N—H⋯S hydrogen bonds, resulting in the formation of e...

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Detalles Bibliográficos
Autores principales: Ali, Saqib, Hameed, Shahid, Luqman, Ahmad, Akhtar, Tashfeen, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979520/
https://www.ncbi.nlm.nih.gov/pubmed/21579372
http://dx.doi.org/10.1107/S1600536810015813
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author Ali, Saqib
Hameed, Shahid
Luqman, Ahmad
Akhtar, Tashfeen
Parvez, Masood
author_facet Ali, Saqib
Hameed, Shahid
Luqman, Ahmad
Akhtar, Tashfeen
Parvez, Masood
author_sort Ali, Saqib
collection PubMed
description In the title mol­ecule, C(8)H(9)NS, the mean plane of the carbothio­amide group is twisted slightly with respect to the mean plane of the benzene ring, making a dihedral angle of 17.03 (10)°. The crystal structure is stabilized by inter­molecular N—H⋯S hydrogen bonds, resulting in the formation of eight-membered rings lying about inversion centers and representing R (2) (2)(8) and R (4) (2)(8) motifs. Futhermore, these hydrogen bonds build up chains parallel to the b axis.
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spelling pubmed-29795202010-12-30 4-Methyl­benzene­carbothio­amide Ali, Saqib Hameed, Shahid Luqman, Ahmad Akhtar, Tashfeen Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(8)H(9)NS, the mean plane of the carbothio­amide group is twisted slightly with respect to the mean plane of the benzene ring, making a dihedral angle of 17.03 (10)°. The crystal structure is stabilized by inter­molecular N—H⋯S hydrogen bonds, resulting in the formation of eight-membered rings lying about inversion centers and representing R (2) (2)(8) and R (4) (2)(8) motifs. Futhermore, these hydrogen bonds build up chains parallel to the b axis. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979520/ /pubmed/21579372 http://dx.doi.org/10.1107/S1600536810015813 Text en © Ali et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, Saqib
Hameed, Shahid
Luqman, Ahmad
Akhtar, Tashfeen
Parvez, Masood
4-Methyl­benzene­carbothio­amide
title 4-Methyl­benzene­carbothio­amide
title_full 4-Methyl­benzene­carbothio­amide
title_fullStr 4-Methyl­benzene­carbothio­amide
title_full_unstemmed 4-Methyl­benzene­carbothio­amide
title_short 4-Methyl­benzene­carbothio­amide
title_sort 4-methyl­benzene­carbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979520/
https://www.ncbi.nlm.nih.gov/pubmed/21579372
http://dx.doi.org/10.1107/S1600536810015813
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AT hameedshahid 4methylbenzenecarbothioamide
AT luqmanahmad 4methylbenzenecarbothioamide
AT akhtartashfeen 4methylbenzenecarbothioamide
AT parvezmasood 4methylbenzenecarbothioamide

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