1-De­oxy-1-fluoro-l-galactitol

The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de­oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro­hexane-1,2,3,4,5-penta­ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In t...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Best, Daniel, Izumori, Ken, Wilson, Francis X., Weymouth-Wilson, Alexander C., Fleet, George W. J., Thompson, Amber L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979521/
https://www.ncbi.nlm.nih.gov/pubmed/21579420
http://dx.doi.org/10.1107/S1600536810016624
Descripción
Sumario:The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de­oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro­hexane-1,2,3,4,5-penta­ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O—H⋯O and O—H⋯F hydrogen bonds, forming a three-dimensional network with each mol­ecule acting as a donor and acceptor for five hydrogen bonds.

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