1-De­oxy-1-fluoro-l-galactitol

The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de­oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro­hexane-1,2,3,4,5-penta­ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In t...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Best, Daniel, Izumori, Ken, Wilson, Francis X., Weymouth-Wilson, Alexander C., Fleet, George W. J., Thompson, Amber L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979521/
https://www.ncbi.nlm.nih.gov/pubmed/21579420
http://dx.doi.org/10.1107/S1600536810016624
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author Jenkinson, Sarah F.
Best, Daniel
Izumori, Ken
Wilson, Francis X.
Weymouth-Wilson, Alexander C.
Fleet, George W. J.
Thompson, Amber L.
author_facet Jenkinson, Sarah F.
Best, Daniel
Izumori, Ken
Wilson, Francis X.
Weymouth-Wilson, Alexander C.
Fleet, George W. J.
Thompson, Amber L.
author_sort Jenkinson, Sarah F.
collection PubMed
description The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de­oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro­hexane-1,2,3,4,5-penta­ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O—H⋯O and O—H⋯F hydrogen bonds, forming a three-dimensional network with each mol­ecule acting as a donor and acceptor for five hydrogen bonds.
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spelling pubmed-29795212010-12-30 1-De­oxy-1-fluoro-l-galactitol Jenkinson, Sarah F. Best, Daniel Izumori, Ken Wilson, Francis X. Weymouth-Wilson, Alexander C. Fleet, George W. J. Thompson, Amber L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de­oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro­hexane-1,2,3,4,5-penta­ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O—H⋯O and O—H⋯F hydrogen bonds, forming a three-dimensional network with each mol­ecule acting as a donor and acceptor for five hydrogen bonds. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979521/ /pubmed/21579420 http://dx.doi.org/10.1107/S1600536810016624 Text en © Jenkinson et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jenkinson, Sarah F.
Best, Daniel
Izumori, Ken
Wilson, Francis X.
Weymouth-Wilson, Alexander C.
Fleet, George W. J.
Thompson, Amber L.
1-De­oxy-1-fluoro-l-galactitol
title 1-De­oxy-1-fluoro-l-galactitol
title_full 1-De­oxy-1-fluoro-l-galactitol
title_fullStr 1-De­oxy-1-fluoro-l-galactitol
title_full_unstemmed 1-De­oxy-1-fluoro-l-galactitol
title_short 1-De­oxy-1-fluoro-l-galactitol
title_sort 1-de­oxy-1-fluoro-l-galactitol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979521/
https://www.ncbi.nlm.nih.gov/pubmed/21579420
http://dx.doi.org/10.1107/S1600536810016624
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AT bestdaniel 1deoxy1fluorolgalactitol
AT izumoriken 1deoxy1fluorolgalactitol
AT wilsonfrancisx 1deoxy1fluorolgalactitol
AT weymouthwilsonalexanderc 1deoxy1fluorolgalactitol
AT fleetgeorgewj 1deoxy1fluorolgalactitol
AT thompsonamberl 1deoxy1fluorolgalactitol

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