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2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide

In the title mol­ecule, C(18)H(17)N(5)O(3)S(2), the heterocyclic thia­zine ring adopts a twist boat conformation, with the S and N atoms displaced by 0.480 (7) and 0.205 (8) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The pyrazole and benzene rings are ti...

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Detalles Bibliográficos
Autores principales: Ahmad, Matloob, Siddiqui, Hamid Latif, Khan, Altaf Hussain, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979531/
https://www.ncbi.nlm.nih.gov/pubmed/21579367
http://dx.doi.org/10.1107/S1600536810015084
Descripción
Sumario:In the title mol­ecule, C(18)H(17)N(5)O(3)S(2), the heterocyclic thia­zine ring adopts a twist boat conformation, with the S and N atoms displaced by 0.480 (7) and 0.205 (8) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The pyrazole and benzene rings are tilted at an angle of 10.9 (2)° with respect to one another. The crystal structure is stabilized by inter­molecular N—H⋯O and C—H⋯N hydrogen bonds, resulting in dimers forming nine-membered rings of graph-set motif R (2) (2)(9). In addition, inter­molecular C—H⋯O inter­actions result in chains of mol­ecules along the c axis, further consolidating the crystal packing.