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2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide

In the title mol­ecule, C(18)H(17)N(5)O(3)S(2), the heterocyclic thia­zine ring adopts a twist boat conformation, with the S and N atoms displaced by 0.480 (7) and 0.205 (8) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The pyrazole and benzene rings are ti...

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Autores principales: Ahmad, Matloob, Siddiqui, Hamid Latif, Khan, Altaf Hussain, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979531/
https://www.ncbi.nlm.nih.gov/pubmed/21579367
http://dx.doi.org/10.1107/S1600536810015084
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author Ahmad, Matloob
Siddiqui, Hamid Latif
Khan, Altaf Hussain
Parvez, Masood
author_facet Ahmad, Matloob
Siddiqui, Hamid Latif
Khan, Altaf Hussain
Parvez, Masood
author_sort Ahmad, Matloob
collection PubMed
description In the title mol­ecule, C(18)H(17)N(5)O(3)S(2), the heterocyclic thia­zine ring adopts a twist boat conformation, with the S and N atoms displaced by 0.480 (7) and 0.205 (8) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The pyrazole and benzene rings are tilted at an angle of 10.9 (2)° with respect to one another. The crystal structure is stabilized by inter­molecular N—H⋯O and C—H⋯N hydrogen bonds, resulting in dimers forming nine-membered rings of graph-set motif R (2) (2)(9). In addition, inter­molecular C—H⋯O inter­actions result in chains of mol­ecules along the c axis, further consolidating the crystal packing.
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spelling pubmed-29795312010-12-30 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide Ahmad, Matloob Siddiqui, Hamid Latif Khan, Altaf Hussain Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(18)H(17)N(5)O(3)S(2), the heterocyclic thia­zine ring adopts a twist boat conformation, with the S and N atoms displaced by 0.480 (7) and 0.205 (8) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The pyrazole and benzene rings are tilted at an angle of 10.9 (2)° with respect to one another. The crystal structure is stabilized by inter­molecular N—H⋯O and C—H⋯N hydrogen bonds, resulting in dimers forming nine-membered rings of graph-set motif R (2) (2)(9). In addition, inter­molecular C—H⋯O inter­actions result in chains of mol­ecules along the c axis, further consolidating the crystal packing. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979531/ /pubmed/21579367 http://dx.doi.org/10.1107/S1600536810015084 Text en © Ahmad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ahmad, Matloob
Siddiqui, Hamid Latif
Khan, Altaf Hussain
Parvez, Masood
2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide
title 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide
title_full 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide
title_fullStr 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide
title_full_unstemmed 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide
title_short 2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-N′-(2-thienylmethyl­idene)acetohydrazide
title_sort 2-(3,4-dimethyl-5,5-dioxo-2h,4h-pyrazolo[4,3-c][1,2]benzothia­zin-2-yl)-n′-(2-thienylmethyl­idene)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979531/
https://www.ncbi.nlm.nih.gov/pubmed/21579367
http://dx.doi.org/10.1107/S1600536810015084
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