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2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid
In the title compound, C(15)H(13)N(3)O(4), the pyridine and benzene rings are nearly perpendicular [dihedral angle = 84.24 (5)°]. In the crystal structure, classical O—H⋯N hydrogen bonding between the OH group of the carboxyl unit and a neighbouring pyridine ring N atom and N—H⋯O hydrogen bonding be...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979532/ https://www.ncbi.nlm.nih.gov/pubmed/21579430 http://dx.doi.org/10.1107/S1600536810017083 |
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author | Xia, Jin Hong Liu, Bao Yu Liu, Zheng |
author_facet | Xia, Jin Hong Liu, Bao Yu Liu, Zheng |
author_sort | Xia, Jin Hong |
collection | PubMed |
description | In the title compound, C(15)H(13)N(3)O(4), the pyridine and benzene rings are nearly perpendicular [dihedral angle = 84.24 (5)°]. In the crystal structure, classical O—H⋯N hydrogen bonding between the OH group of the carboxyl unit and a neighbouring pyridine ring N atom and N—H⋯O hydrogen bonding between the imine NH group and a neighbouring O atom of an acyl unit, together with complementary non-classical C—H⋯O hydrogen bonds between carboxyl O atoms and neighbouring CH groups, link the molecules into a three-dimensional system. |
format | Text |
id | pubmed-2979532 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29795322010-12-30 2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid Xia, Jin Hong Liu, Bao Yu Liu, Zheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(13)N(3)O(4), the pyridine and benzene rings are nearly perpendicular [dihedral angle = 84.24 (5)°]. In the crystal structure, classical O—H⋯N hydrogen bonding between the OH group of the carboxyl unit and a neighbouring pyridine ring N atom and N—H⋯O hydrogen bonding between the imine NH group and a neighbouring O atom of an acyl unit, together with complementary non-classical C—H⋯O hydrogen bonds between carboxyl O atoms and neighbouring CH groups, link the molecules into a three-dimensional system. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979532/ /pubmed/21579430 http://dx.doi.org/10.1107/S1600536810017083 Text en © Xia et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Xia, Jin Hong Liu, Bao Yu Liu, Zheng 2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid |
title | 2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid |
title_full | 2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid |
title_fullStr | 2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid |
title_full_unstemmed | 2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid |
title_short | 2-(2-{[2-(4-Pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid |
title_sort | 2-(2-{[2-(4-pyridylcarbonyl)hydrazinylidene]methyl}phenoxy)acetic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979532/ https://www.ncbi.nlm.nih.gov/pubmed/21579430 http://dx.doi.org/10.1107/S1600536810017083 |
work_keys_str_mv | AT xiajinhong 2224pyridylcarbonylhydrazinylidenemethylphenoxyaceticacid AT liubaoyu 2224pyridylcarbonylhydrazinylidenemethylphenoxyaceticacid AT liuzheng 2224pyridylcarbonylhydrazinylidenemethylphenoxyaceticacid |