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Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2) N,P}methylpalladium(II) dichloromethane hemisolvate
In the title compound, [Pd(CH(3))Cl(C(25)H(22)NPS)]·0.5C(2)H(2)Cl(2), the Pd(II) atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disor...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979533/ https://www.ncbi.nlm.nih.gov/pubmed/21579327 http://dx.doi.org/10.1107/S1600536810017824 |
| _version_ | 1782191435849662464 |
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| author | Onani, Martin O. Motswainyana, William M. Iwuoha, Emmanuel I. Darkwa, James Lalancette, Roger A. |
| author_facet | Onani, Martin O. Motswainyana, William M. Iwuoha, Emmanuel I. Darkwa, James Lalancette, Roger A. |
| author_sort | Onani, Martin O. |
| collection | PubMed |
| description | In the title compound, [Pd(CH(3))Cl(C(25)H(22)NPS)]·0.5C(2)H(2)Cl(2), the Pd(II) atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disordered over two orientations and the dichloromethane solvent molecule is disordered about an inversion centre. |
| format | Text |
| id | pubmed-2979533 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29795332010-12-30 Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2) N,P}methylpalladium(II) dichloromethane hemisolvate Onani, Martin O. Motswainyana, William M. Iwuoha, Emmanuel I. Darkwa, James Lalancette, Roger A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(CH(3))Cl(C(25)H(22)NPS)]·0.5C(2)H(2)Cl(2), the Pd(II) atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disordered over two orientations and the dichloromethane solvent molecule is disordered about an inversion centre. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979533/ /pubmed/21579327 http://dx.doi.org/10.1107/S1600536810017824 Text en © Onani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Onani, Martin O. Motswainyana, William M. Iwuoha, Emmanuel I. Darkwa, James Lalancette, Roger A. Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2) N,P}methylpalladium(II) dichloromethane hemisolvate |
| title | Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2)
N,P}methylpalladium(II) dichloromethane hemisolvate |
| title_full | Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2)
N,P}methylpalladium(II) dichloromethane hemisolvate |
| title_fullStr | Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2)
N,P}methylpalladium(II) dichloromethane hemisolvate |
| title_full_unstemmed | Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2)
N,P}methylpalladium(II) dichloromethane hemisolvate |
| title_short | Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2)
N,P}methylpalladium(II) dichloromethane hemisolvate |
| title_sort | chlorido{n-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ(2)
n,p}methylpalladium(ii) dichloromethane hemisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979533/ https://www.ncbi.nlm.nih.gov/pubmed/21579327 http://dx.doi.org/10.1107/S1600536810017824 |
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