Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II)

In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl­pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra­molecular N—H⋯O hydrogen bonds occu...

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Detalles Bibliográficos
Autores principales: Kaabi, Kamel, El Glaoui, Meher, Pereira Silva, P. S., Ramos Silva, M., Ben Nasr, Cherif
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979534/
https://www.ncbi.nlm.nih.gov/pubmed/21579276
http://dx.doi.org/10.1107/S1600536810015874
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author Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S.
Ramos Silva, M.
Ben Nasr, Cherif
author_facet Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S.
Ramos Silva, M.
Ben Nasr, Cherif
author_sort Kaabi, Kamel
collection PubMed
description In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl­pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra­molecular N—H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups.
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spelling pubmed-29795342010-12-30 Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II) Kaabi, Kamel El Glaoui, Meher Pereira Silva, P. S. Ramos Silva, M. Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NO(3))(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is eight-coordinated by two amine N atoms and two O atoms from two zwitterionic, biodentate 2-amino-6-methyl­pyrimidin-1-ium-4-olate ligands and by four O atoms from two nitrate groups. Intra­molecular N—H⋯O hydrogen bonds occur. The crystal packing is stabilized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, two of which are bifurcated, between the nitrate anions and the organic groups. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979534/ /pubmed/21579276 http://dx.doi.org/10.1107/S1600536810015874 Text en © Kaabi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kaabi, Kamel
El Glaoui, Meher
Pereira Silva, P. S.
Ramos Silva, M.
Ben Nasr, Cherif
Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II)
title Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II)
title_full Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II)
title_fullStr Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II)
title_full_unstemmed Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II)
title_short Bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) N (3),O)bis­(nitrato-κ(2) O,O′)cadmium(II)
title_sort bis(2-amino-6-methyl­pyrimidin-1-ium-4-olate-κ(2) n (3),o)bis­(nitrato-κ(2) o,o′)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979534/
https://www.ncbi.nlm.nih.gov/pubmed/21579276
http://dx.doi.org/10.1107/S1600536810015874
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