Cargando…

3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one

In the title compound, C(19)H(12)FN(3)O(2)S, the chromene ring system and the thia­zole ring are approximately planar [maximum deviations of 0.023 (3) Å and 0.004 (2) Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10) and 26.51 (10)° with respect to the thia­zole and benze...

Descripción completa

Detalles Bibliográficos
Autores principales: Arshad, Afsheen, Osman, Hasnah, Lam, Chan Kit, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979535/
https://www.ncbi.nlm.nih.gov/pubmed/21579518
http://dx.doi.org/10.1107/S1600536810018647
_version_ 1782191436321521664
author Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Arshad, Afsheen
collection PubMed
description In the title compound, C(19)H(12)FN(3)O(2)S, the chromene ring system and the thia­zole ring are approximately planar [maximum deviations of 0.023 (3) Å and 0.004 (2) Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10) and 26.51 (10)° with respect to the thia­zole and benzene rings, respectively, while the thia­zole ring makes a dihedral angle of 23.07 (12)° with the benzene ring. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is consolidated by inter­molecular N—H⋯O hydrogen bonds, which link the mol­ecules into chains parallel to [100], and by C—H⋯π and π–π [centroid–centroid distance = 3.4954 (15) Å] stacking inter­actions.
format Text
id pubmed-2979535
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29795352010-12-30 3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(12)FN(3)O(2)S, the chromene ring system and the thia­zole ring are approximately planar [maximum deviations of 0.023 (3) Å and 0.004 (2) Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10) and 26.51 (10)° with respect to the thia­zole and benzene rings, respectively, while the thia­zole ring makes a dihedral angle of 23.07 (12)° with the benzene ring. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is consolidated by inter­molecular N—H⋯O hydrogen bonds, which link the mol­ecules into chains parallel to [100], and by C—H⋯π and π–π [centroid–centroid distance = 3.4954 (15) Å] stacking inter­actions. International Union of Crystallography 2010-05-26 /pmc/articles/PMC2979535/ /pubmed/21579518 http://dx.doi.org/10.1107/S1600536810018647 Text en © Arshad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Quah, Ching Kheng
Fun, Hoong-Kun
3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one
title 3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one
title_full 3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one
title_fullStr 3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one
title_full_unstemmed 3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one
title_short 3-{2-[2-(2-Fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one
title_sort 3-{2-[2-(2-fluoro­benzyl­idene)hydrazin­yl]-1,3-thia­zol-4-yl}-2h-chromen-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979535/
https://www.ncbi.nlm.nih.gov/pubmed/21579518
http://dx.doi.org/10.1107/S1600536810018647
work_keys_str_mv AT arshadafsheen 3222fluorobenzylidenehydrazinyl13thiazol4yl2hchromen2one
AT osmanhasnah 3222fluorobenzylidenehydrazinyl13thiazol4yl2hchromen2one
AT lamchankit 3222fluorobenzylidenehydrazinyl13thiazol4yl2hchromen2one
AT quahchingkheng 3222fluorobenzylidenehydrazinyl13thiazol4yl2hchromen2one
AT funhoongkun 3222fluorobenzylidenehydrazinyl13thiazol4yl2hchromen2one