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3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one
In the title compound, C(19)H(12)FN(3)O(2)S, the chromene ring system and the thiazole ring are approximately planar [maximum deviations of 0.023 (3) Å and 0.004 (2) Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10) and 26.51 (10)° with respect to the thiazole and benze...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979535/ https://www.ncbi.nlm.nih.gov/pubmed/21579518 http://dx.doi.org/10.1107/S1600536810018647 |
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author | Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Arshad, Afsheen |
collection | PubMed |
description | In the title compound, C(19)H(12)FN(3)O(2)S, the chromene ring system and the thiazole ring are approximately planar [maximum deviations of 0.023 (3) Å and 0.004 (2) Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10) and 26.51 (10)° with respect to the thiazole and benzene rings, respectively, while the thiazole ring makes a dihedral angle of 23.07 (12)° with the benzene ring. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is consolidated by intermolecular N—H⋯O hydrogen bonds, which link the molecules into chains parallel to [100], and by C—H⋯π and π–π [centroid–centroid distance = 3.4954 (15) Å] stacking interactions. |
format | Text |
id | pubmed-2979535 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29795352010-12-30 3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(12)FN(3)O(2)S, the chromene ring system and the thiazole ring are approximately planar [maximum deviations of 0.023 (3) Å and 0.004 (2) Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10) and 26.51 (10)° with respect to the thiazole and benzene rings, respectively, while the thiazole ring makes a dihedral angle of 23.07 (12)° with the benzene ring. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is consolidated by intermolecular N—H⋯O hydrogen bonds, which link the molecules into chains parallel to [100], and by C—H⋯π and π–π [centroid–centroid distance = 3.4954 (15) Å] stacking interactions. International Union of Crystallography 2010-05-26 /pmc/articles/PMC2979535/ /pubmed/21579518 http://dx.doi.org/10.1107/S1600536810018647 Text en © Arshad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun 3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one |
title | 3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one |
title_full | 3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one |
title_fullStr | 3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one |
title_full_unstemmed | 3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one |
title_short | 3-{2-[2-(2-Fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one |
title_sort | 3-{2-[2-(2-fluorobenzylidene)hydrazinyl]-1,3-thiazol-4-yl}-2h-chromen-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979535/ https://www.ncbi.nlm.nih.gov/pubmed/21579518 http://dx.doi.org/10.1107/S1600536810018647 |
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