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2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate

In the title compound, C(16)H(16)N(2)O(4)·H(2)O, the dihedral angle between the two benzene rings is 12.4 (2)° and the mol­ecule adopts an E configuration with respect to the C=N bond. There are intra­molecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone mol­ecule, which both generate S(6) rings...

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Detalles Bibliográficos
Autores principales: Han, You-Yue, Li, Yong-Hong, Zhao, Qiu-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979542/
https://www.ncbi.nlm.nih.gov/pubmed/21579429
http://dx.doi.org/10.1107/S1600536810016855
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author Han, You-Yue
Li, Yong-Hong
Zhao, Qiu-Rong
author_facet Han, You-Yue
Li, Yong-Hong
Zhao, Qiu-Rong
author_sort Han, You-Yue
collection PubMed
description In the title compound, C(16)H(16)N(2)O(4)·H(2)O, the dihedral angle between the two benzene rings is 12.4 (2)° and the mol­ecule adopts an E configuration with respect to the C=N bond. There are intra­molecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone mol­ecule, which both generate S(6) rings. In the crystal structure, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the ab plane. The crystal studied was a non-merohedral twin with a domain ratio of 0.887 (3):0.113 (3).
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spelling pubmed-29795422010-12-30 2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate Han, You-Yue Li, Yong-Hong Zhao, Qiu-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)N(2)O(4)·H(2)O, the dihedral angle between the two benzene rings is 12.4 (2)° and the mol­ecule adopts an E configuration with respect to the C=N bond. There are intra­molecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone mol­ecule, which both generate S(6) rings. In the crystal structure, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the ab plane. The crystal studied was a non-merohedral twin with a domain ratio of 0.887 (3):0.113 (3). International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979542/ /pubmed/21579429 http://dx.doi.org/10.1107/S1600536810016855 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Han, You-Yue
Li, Yong-Hong
Zhao, Qiu-Rong
2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate
title 2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate
title_full 2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate
title_fullStr 2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate
title_full_unstemmed 2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate
title_short 2-Hydr­oxy-N′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate
title_sort 2-hydr­oxy-n′-(2-hydr­oxy-4-methoxy­benzyl­idene)-3-methyl­benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979542/
https://www.ncbi.nlm.nih.gov/pubmed/21579429
http://dx.doi.org/10.1107/S1600536810016855
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