Cargando…
2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate
In the title compound, C(16)H(16)N(2)O(4)·H(2)O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone molecule, which both generate S(6) rings...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979542/ https://www.ncbi.nlm.nih.gov/pubmed/21579429 http://dx.doi.org/10.1107/S1600536810016855 |
_version_ | 1782191437990854656 |
---|---|
author | Han, You-Yue Li, Yong-Hong Zhao, Qiu-Rong |
author_facet | Han, You-Yue Li, Yong-Hong Zhao, Qiu-Rong |
author_sort | Han, You-Yue |
collection | PubMed |
description | In the title compound, C(16)H(16)N(2)O(4)·H(2)O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone molecule, which both generate S(6) rings. In the crystal structure, molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the ab plane. The crystal studied was a non-merohedral twin with a domain ratio of 0.887 (3):0.113 (3). |
format | Text |
id | pubmed-2979542 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29795422010-12-30 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate Han, You-Yue Li, Yong-Hong Zhao, Qiu-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)N(2)O(4)·H(2)O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone molecule, which both generate S(6) rings. In the crystal structure, molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the ab plane. The crystal studied was a non-merohedral twin with a domain ratio of 0.887 (3):0.113 (3). International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979542/ /pubmed/21579429 http://dx.doi.org/10.1107/S1600536810016855 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Han, You-Yue Li, Yong-Hong Zhao, Qiu-Rong 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
title | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
title_full | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
title_fullStr | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
title_full_unstemmed | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
title_short | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
title_sort | 2-hydroxy-n′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979542/ https://www.ncbi.nlm.nih.gov/pubmed/21579429 http://dx.doi.org/10.1107/S1600536810016855 |
work_keys_str_mv | AT hanyouyue 2hydroxyn2hydroxy4methoxybenzylidene3methylbenzohydrazidemonohydrate AT liyonghong 2hydroxyn2hydroxy4methoxybenzylidene3methylbenzohydrazidemonohydrate AT zhaoqiurong 2hydroxyn2hydroxy4methoxybenzylidene3methylbenzohydrazidemonohydrate |