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Tetra-μ-acetato-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)europium(III)]
In the title centrosymmetric dinuclear Eu(III) complex, [Eu(2)(CH(3)COO)(6)(C(12)H(8)N(2))(2)], each Eu(III) cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979550/ https://www.ncbi.nlm.nih.gov/pubmed/21579268 http://dx.doi.org/10.1107/S1600536810015680 |
| _version_ | 1782191439971614720 |
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| author | Liu, Wen-Jing Li, Zhao-Yang Wei, Zhi-Qiang Yue, Shan-Tang |
| author_facet | Liu, Wen-Jing Li, Zhao-Yang Wei, Zhi-Qiang Yue, Shan-Tang |
| author_sort | Liu, Wen-Jing |
| collection | PubMed |
| description | In the title centrosymmetric dinuclear Eu(III) complex, [Eu(2)(CH(3)COO)(6)(C(12)H(8)N(2))(2)], each Eu(III) cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two Eu(III) cations to form the dinuclear complex, with an Eu⋯Eu distance of 3.9409 (8) Å. Weak intermolecular C—H⋯O hydrogen bonding is present in the crystal structure. |
| format | Text |
| id | pubmed-2979550 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29795502010-12-30 Tetra-μ-acetato-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)europium(III)] Liu, Wen-Jing Li, Zhao-Yang Wei, Zhi-Qiang Yue, Shan-Tang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear Eu(III) complex, [Eu(2)(CH(3)COO)(6)(C(12)H(8)N(2))(2)], each Eu(III) cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two Eu(III) cations to form the dinuclear complex, with an Eu⋯Eu distance of 3.9409 (8) Å. Weak intermolecular C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979550/ /pubmed/21579268 http://dx.doi.org/10.1107/S1600536810015680 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Wen-Jing Li, Zhao-Yang Wei, Zhi-Qiang Yue, Shan-Tang Tetra-μ-acetato-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)europium(III)] |
| title | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_full | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_fullStr | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_full_unstemmed | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_short | Tetra-μ-acetato-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)europium(III)] |
| title_sort | tetra-μ-acetato-κ(4)
o:o′;κ(3)
o,o′:o′;κ(3)
o:o,o′-bis[(acetato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)europium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979550/ https://www.ncbi.nlm.nih.gov/pubmed/21579268 http://dx.doi.org/10.1107/S1600536810015680 |
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