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2-Amino-5-chloropyridinium 2-carboxyacetate
The title salt, C(5)H(6)ClN(2) (+)·C(3)H(3)O(4) (−), contains two cations and two anions in the asymmetric unit. Both 2-amino-5-chloropyridinium ions are protonated at their pyridine N atoms and both hydrogen malonate ions feature an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979552/ https://www.ncbi.nlm.nih.gov/pubmed/21579558 http://dx.doi.org/10.1107/S1600536810019677 |
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author | Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | The title salt, C(5)H(6)ClN(2) (+)·C(3)H(3)O(4) (−), contains two cations and two anions in the asymmetric unit. Both 2-amino-5-chloropyridinium ions are protonated at their pyridine N atoms and both hydrogen malonate ions feature an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring motif and results in a folded conformation. In the crystal structure, the cations and anions are linked via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming chains propagating in [010], which are cross-linked by further C—H⋯O interactions. |
format | Text |
id | pubmed-2979552 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29795522010-12-30 2-Amino-5-chloropyridinium 2-carboxyacetate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(5)H(6)ClN(2) (+)·C(3)H(3)O(4) (−), contains two cations and two anions in the asymmetric unit. Both 2-amino-5-chloropyridinium ions are protonated at their pyridine N atoms and both hydrogen malonate ions feature an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring motif and results in a folded conformation. In the crystal structure, the cations and anions are linked via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming chains propagating in [010], which are cross-linked by further C—H⋯O interactions. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979552/ /pubmed/21579558 http://dx.doi.org/10.1107/S1600536810019677 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Fun, Hoong-Kun 2-Amino-5-chloropyridinium 2-carboxyacetate |
title | 2-Amino-5-chloropyridinium 2-carboxyacetate |
title_full | 2-Amino-5-chloropyridinium 2-carboxyacetate |
title_fullStr | 2-Amino-5-chloropyridinium 2-carboxyacetate |
title_full_unstemmed | 2-Amino-5-chloropyridinium 2-carboxyacetate |
title_short | 2-Amino-5-chloropyridinium 2-carboxyacetate |
title_sort | 2-amino-5-chloropyridinium 2-carboxyacetate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979552/ https://www.ncbi.nlm.nih.gov/pubmed/21579558 http://dx.doi.org/10.1107/S1600536810019677 |
work_keys_str_mv | AT hemamalinimadhukar 2amino5chloropyridinium2carboxyacetate AT funhoongkun 2amino5chloropyridinium2carboxyacetate |