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2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate

The title salt, C(5)H(6)ClN(2) (+)·C(3)H(3)O(4) (−), contains two cations and two anions in the asymmetric unit. Both 2-amino-5-chloro­pyridinium ions are protonated at their pyridine N atoms and both hydrogen malonate ions feature an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) ring...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979552/
https://www.ncbi.nlm.nih.gov/pubmed/21579558
http://dx.doi.org/10.1107/S1600536810019677
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description The title salt, C(5)H(6)ClN(2) (+)·C(3)H(3)O(4) (−), contains two cations and two anions in the asymmetric unit. Both 2-amino-5-chloro­pyridinium ions are protonated at their pyridine N atoms and both hydrogen malonate ions feature an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) ring motif and results in a folded conformation. In the crystal structure, the cations and anions are linked via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming chains propagating in [010], which are cross-linked by further C—H⋯O inter­actions.
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spelling pubmed-29795522010-12-30 2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(5)H(6)ClN(2) (+)·C(3)H(3)O(4) (−), contains two cations and two anions in the asymmetric unit. Both 2-amino-5-chloro­pyridinium ions are protonated at their pyridine N atoms and both hydrogen malonate ions feature an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) ring motif and results in a folded conformation. In the crystal structure, the cations and anions are linked via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming chains propagating in [010], which are cross-linked by further C—H⋯O inter­actions. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979552/ /pubmed/21579558 http://dx.doi.org/10.1107/S1600536810019677 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate
title 2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate
title_full 2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate
title_fullStr 2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate
title_full_unstemmed 2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate
title_short 2-Amino-5-chloro­pyridinium 2-carb­oxy­acetate
title_sort 2-amino-5-chloro­pyridinium 2-carb­oxy­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979552/
https://www.ncbi.nlm.nih.gov/pubmed/21579558
http://dx.doi.org/10.1107/S1600536810019677
work_keys_str_mv AT hemamalinimadhukar 2amino5chloropyridinium2carboxyacetate
AT funhoongkun 2amino5chloropyridinium2carboxyacetate