Cargando…
(2,2′-Bipyridine-κ(2) N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II)
In the molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2))(C(2)H(6)OS)], the Zn(II) atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from one 2,2′-bipyridine, one O atom from one dimethylsulfoxide molecule and two Br atoms. Intermolecular π–π stacking...
| Autor principal: | |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979554/ https://www.ncbi.nlm.nih.gov/pubmed/21579317 http://dx.doi.org/10.1107/S1600536810017551 |
| _version_ | 1782191440904847360 |
|---|---|
| author | Esmhosseini, Majid |
| author_facet | Esmhosseini, Majid |
| author_sort | Esmhosseini, Majid |
| collection | PubMed |
| description | In the molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2))(C(2)H(6)OS)], the Zn(II) atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from one 2,2′-bipyridine, one O atom from one dimethylsulfoxide molecule and two Br atoms. Intermolecular π–π stacking between parallel pyridine rings [face-to-face distance 3.32 (4) Å] and C—H⋯Br and C—H⋯O hydrogen-bonding interactions are present in the crystal structure. |
| format | Text |
| id | pubmed-2979554 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29795542010-12-30 (2,2′-Bipyridine-κ(2) N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II) Esmhosseini, Majid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2))(C(2)H(6)OS)], the Zn(II) atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from one 2,2′-bipyridine, one O atom from one dimethylsulfoxide molecule and two Br atoms. Intermolecular π–π stacking between parallel pyridine rings [face-to-face distance 3.32 (4) Å] and C—H⋯Br and C—H⋯O hydrogen-bonding interactions are present in the crystal structure. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979554/ /pubmed/21579317 http://dx.doi.org/10.1107/S1600536810017551 Text en © Majid Esmhosseini 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Esmhosseini, Majid (2,2′-Bipyridine-κ(2) N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II) |
| title | (2,2′-Bipyridine-κ(2)
N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II) |
| title_full | (2,2′-Bipyridine-κ(2)
N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II) |
| title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II) |
| title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II) |
| title_short | (2,2′-Bipyridine-κ(2)
N,N′)dibromido(dimethyl sulfoxide-κO)zinc(II) |
| title_sort | (2,2′-bipyridine-κ(2)
n,n′)dibromido(dimethyl sulfoxide-κo)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979554/ https://www.ncbi.nlm.nih.gov/pubmed/21579317 http://dx.doi.org/10.1107/S1600536810017551 |
| work_keys_str_mv | AT esmhosseinimajid 22bipyridinek2nndibromidodimethylsulfoxidekozincii |