Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate

The title compound, C(16)H(14)O(5), was prepared from the reaction of 3-carbethoxy­coumarin with furan in the presence of AlCl(3) as catalyst. In the crystal, inter­molecular C—H⋯O hydrogen-bonding inter­actions between four mol­ecules lead to a tetra­mer in the unit cell. The furan ring is anti­per...

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Detalles Bibliográficos
Autores principales: Prabhakar, Maddela, Reddy, J. S. N., Kumar, N. Ravi, Ganesh, S. Viswanadha, Solomon, K. Anand
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979556/
https://www.ncbi.nlm.nih.gov/pubmed/21579405
http://dx.doi.org/10.1107/S1600536810016193
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author Prabhakar, Maddela
Reddy, J. S. N.
Kumar, N. Ravi
Ganesh, S. Viswanadha
Solomon, K. Anand
author_facet Prabhakar, Maddela
Reddy, J. S. N.
Kumar, N. Ravi
Ganesh, S. Viswanadha
Solomon, K. Anand
author_sort Prabhakar, Maddela
collection PubMed
description The title compound, C(16)H(14)O(5), was prepared from the reaction of 3-carbethoxy­coumarin with furan in the presence of AlCl(3) as catalyst. In the crystal, inter­molecular C—H⋯O hydrogen-bonding inter­actions between four mol­ecules lead to a tetra­mer in the unit cell. The furan ring is anti­periplanar [C—C—C—O = 167.9 (13)°] and the ethoxy­carbonyl group is (−)anti­clinal [C—C—C—O = −128.6 (14)°] to the lactone ring.
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spelling pubmed-29795562010-12-30 Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate Prabhakar, Maddela Reddy, J. S. N. Kumar, N. Ravi Ganesh, S. Viswanadha Solomon, K. Anand Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(14)O(5), was prepared from the reaction of 3-carbethoxy­coumarin with furan in the presence of AlCl(3) as catalyst. In the crystal, inter­molecular C—H⋯O hydrogen-bonding inter­actions between four mol­ecules lead to a tetra­mer in the unit cell. The furan ring is anti­periplanar [C—C—C—O = 167.9 (13)°] and the ethoxy­carbonyl group is (−)anti­clinal [C—C—C—O = −128.6 (14)°] to the lactone ring. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979556/ /pubmed/21579405 http://dx.doi.org/10.1107/S1600536810016193 Text en © Prabhakar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prabhakar, Maddela
Reddy, J. S. N.
Kumar, N. Ravi
Ganesh, S. Viswanadha
Solomon, K. Anand
Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate
title Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate
title_full Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate
title_fullStr Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate
title_full_unstemmed Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate
title_short Ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate
title_sort ethyl 4-(2-fur­yl)-2-oxochroman-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979556/
https://www.ncbi.nlm.nih.gov/pubmed/21579405
http://dx.doi.org/10.1107/S1600536810016193
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AT reddyjsn ethyl42furyl2oxochroman3carboxylate
AT kumarnravi ethyl42furyl2oxochroman3carboxylate
AT ganeshsviswanadha ethyl42furyl2oxochroman3carboxylate
AT solomonkanand ethyl42furyl2oxochroman3carboxylate

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