5,22-Stigmastadien-3β-yl p-toluene­sulfonate

The asymmetric unit of the title compound {systematic name: (3S,8S,9S,10R,13R,14S,17R)-17-[(E,2R,5S)-5-ethyl-6-methyl­hept-3-en-2-yl]-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodeca­hydro-1H-cyclo­penta­[a]phenanthren-3-yl p-toluene­sulfonate}, C(36)H(54)O(3)S, comprises two independent mol­ecul...

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Detalles Bibliográficos
Autores principales: Ketuly, Kamal Aziz, Hadi, A. Hamid A., Khaledi, Hamid, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979557/
https://www.ncbi.nlm.nih.gov/pubmed/21579426
http://dx.doi.org/10.1107/S1600536810016661
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author Ketuly, Kamal Aziz
Hadi, A. Hamid A.
Khaledi, Hamid
Tiekink, Edward R. T.
author_facet Ketuly, Kamal Aziz
Hadi, A. Hamid A.
Khaledi, Hamid
Tiekink, Edward R. T.
author_sort Ketuly, Kamal Aziz
collection PubMed
description The asymmetric unit of the title compound {systematic name: (3S,8S,9S,10R,13R,14S,17R)-17-[(E,2R,5S)-5-ethyl-6-methyl­hept-3-en-2-yl]-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodeca­hydro-1H-cyclo­penta­[a]phenanthren-3-yl p-toluene­sulfonate}, C(36)H(54)O(3)S, comprises two independent mol­ecules that differ significantly in terms of the relative orientations of the peripheral groups; the conformation about the C=C bond of the side chain is E. In the crystal, mol­ecules associate into linear supra­molecular chains aligned along the a axis via C—H⋯O inter­actions.
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spelling pubmed-29795572010-12-30 5,22-Stigmastadien-3β-yl p-toluene­sulfonate Ketuly, Kamal Aziz Hadi, A. Hamid A. Khaledi, Hamid Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound {systematic name: (3S,8S,9S,10R,13R,14S,17R)-17-[(E,2R,5S)-5-ethyl-6-methyl­hept-3-en-2-yl]-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodeca­hydro-1H-cyclo­penta­[a]phenanthren-3-yl p-toluene­sulfonate}, C(36)H(54)O(3)S, comprises two independent mol­ecules that differ significantly in terms of the relative orientations of the peripheral groups; the conformation about the C=C bond of the side chain is E. In the crystal, mol­ecules associate into linear supra­molecular chains aligned along the a axis via C—H⋯O inter­actions. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979557/ /pubmed/21579426 http://dx.doi.org/10.1107/S1600536810016661 Text en © Ketuly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ketuly, Kamal Aziz
Hadi, A. Hamid A.
Khaledi, Hamid
Tiekink, Edward R. T.
5,22-Stigmastadien-3β-yl p-toluene­sulfonate
title 5,22-Stigmastadien-3β-yl p-toluene­sulfonate
title_full 5,22-Stigmastadien-3β-yl p-toluene­sulfonate
title_fullStr 5,22-Stigmastadien-3β-yl p-toluene­sulfonate
title_full_unstemmed 5,22-Stigmastadien-3β-yl p-toluene­sulfonate
title_short 5,22-Stigmastadien-3β-yl p-toluene­sulfonate
title_sort 5,22-stigmastadien-3β-yl p-toluene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979557/
https://www.ncbi.nlm.nih.gov/pubmed/21579426
http://dx.doi.org/10.1107/S1600536810016661
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AT tiekinkedwardrt 522stigmastadien3bylptoluenesulfonate

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