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Triaqua(1,4,7-triazacyclononane-κ(3) N (1),N (4),N (7))nickel(II) bromide nitrate
In the title half-sandwich compound, [Ni(C(6)H(15)N(3))(H(2)O)(3)]Br(NO(3)), the central Ni(II) ion, lying on a threefold rotation axis, is six-coordinated by three amine N atoms from the face-capping triaza macrocycle and three water O atoms in a slightly distorted octahedral geometry. In the crys...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979567/ https://www.ncbi.nlm.nih.gov/pubmed/21579281 http://dx.doi.org/10.1107/S160053681001620X |
Sumario: | In the title half-sandwich compound, [Ni(C(6)H(15)N(3))(H(2)O)(3)]Br(NO(3)), the central Ni(II) ion, lying on a threefold rotation axis, is six-coordinated by three amine N atoms from the face-capping triaza macrocycle and three water O atoms in a slightly distorted octahedral geometry. In the crystal, O—H⋯O hydrogen bonding and weak O—H⋯Br interactions associate the Ni(II) cations and the counter-ions into a three-dimensional supramolecular network. |
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