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Triaqua­(1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7))nickel(II) bromide nitrate

In the title half-sandwich compound, [Ni(C(6)H(15)N(3))(H(2)O)(3)]Br(NO(3)), the central Ni(II) ion, lying on a threefold rotation axis, is six-coordinated by three amine N atoms from the face-capping triaza macrocycle and three water O atoms in a slightly distorted octa­hedral geometry. In the crys...

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Detalles Bibliográficos
Autores principales: Wen, Changchun, Lu, Jianqi, Zhang, Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979567/
https://www.ncbi.nlm.nih.gov/pubmed/21579281
http://dx.doi.org/10.1107/S160053681001620X
Descripción
Sumario:In the title half-sandwich compound, [Ni(C(6)H(15)N(3))(H(2)O)(3)]Br(NO(3)), the central Ni(II) ion, lying on a threefold rotation axis, is six-coordinated by three amine N atoms from the face-capping triaza macrocycle and three water O atoms in a slightly distorted octa­hedral geometry. In the crystal, O—H⋯O hydrogen bonding and weak O—H⋯Br inter­actions associate the Ni(II) cations and the counter-ions into a three-dimensional supra­molecular network.