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Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2) N (4),N (7))palladium(II) p-toluenesulfonate
The title compound, [PdCl(2)(C(6)H(16)N(3))](C(7)H(7)SO(3)), consists of a Pd(II) atom bonded to two N atoms of the 1,4,7-triazacyclononane (TACN) ligand and two chloride ions, which define a distorted square-planar geometry. The third N atom of the TACN ligand is protonated and hydrogen bonds to...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979570/ https://www.ncbi.nlm.nih.gov/pubmed/21579291 http://dx.doi.org/10.1107/S1600536810016533 |
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author | Anthony, Timothy A. Arman, Hadi D. Walmsley, Judith A. |
author_facet | Anthony, Timothy A. Arman, Hadi D. Walmsley, Judith A. |
author_sort | Anthony, Timothy A. |
collection | PubMed |
description | The title compound, [PdCl(2)(C(6)H(16)N(3))](C(7)H(7)SO(3)), consists of a Pd(II) atom bonded to two N atoms of the 1,4,7-triazacyclononane (TACN) ligand and two chloride ions, which define a distorted square-planar geometry. The third N atom of the TACN ligand is protonated and hydrogen bonds to the p-toluenesulfonate anion. The Cl—Pd—Cl angle is larger than the N—Pd—N angle. The packing is dominated by layers, which are formed by the criss-crossing of two different hydrogen-bonded chains. One chain is composed of hydrogen-bonded Pd(TACNH)Cl(2) (+) cations, while the second is formed through hydrogen bonding between the p-toluenesulfonate anion and the Pd(TACNH)Cl(2) (+) cation. |
format | Text |
id | pubmed-2979570 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29795702010-12-30 Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2) N (4),N (7))palladium(II) p-toluenesulfonate Anthony, Timothy A. Arman, Hadi D. Walmsley, Judith A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(6)H(16)N(3))](C(7)H(7)SO(3)), consists of a Pd(II) atom bonded to two N atoms of the 1,4,7-triazacyclononane (TACN) ligand and two chloride ions, which define a distorted square-planar geometry. The third N atom of the TACN ligand is protonated and hydrogen bonds to the p-toluenesulfonate anion. The Cl—Pd—Cl angle is larger than the N—Pd—N angle. The packing is dominated by layers, which are formed by the criss-crossing of two different hydrogen-bonded chains. One chain is composed of hydrogen-bonded Pd(TACNH)Cl(2) (+) cations, while the second is formed through hydrogen bonding between the p-toluenesulfonate anion and the Pd(TACNH)Cl(2) (+) cation. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979570/ /pubmed/21579291 http://dx.doi.org/10.1107/S1600536810016533 Text en © Anthony et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Anthony, Timothy A. Arman, Hadi D. Walmsley, Judith A. Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2) N (4),N (7))palladium(II) p-toluenesulfonate |
title | Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2)
N
(4),N
(7))palladium(II) p-toluenesulfonate |
title_full | Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2)
N
(4),N
(7))palladium(II) p-toluenesulfonate |
title_fullStr | Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2)
N
(4),N
(7))palladium(II) p-toluenesulfonate |
title_full_unstemmed | Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2)
N
(4),N
(7))palladium(II) p-toluenesulfonate |
title_short | Dichlorido(4,7-diaza-1-azoniacyclononane-κ(2)
N
(4),N
(7))palladium(II) p-toluenesulfonate |
title_sort | dichlorido(4,7-diaza-1-azoniacyclononane-κ(2)
n
(4),n
(7))palladium(ii) p-toluenesulfonate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979570/ https://www.ncbi.nlm.nih.gov/pubmed/21579291 http://dx.doi.org/10.1107/S1600536810016533 |
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