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Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate

The title compound, [PdCl(2)(C(6)H(16)N(3))](C(7)H(7)SO(3)), consists of a Pd(II) atom bonded to two N atoms of the 1,4,7-triaza­cyclo­nonane (TACN) ligand and two chloride ions, which define a distorted square-planar geometry. The third N atom of the TACN ligand is protonated and hydrogen bonds to...

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Detalles Bibliográficos
Autores principales: Anthony, Timothy A., Arman, Hadi D., Walmsley, Judith A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979570/
https://www.ncbi.nlm.nih.gov/pubmed/21579291
http://dx.doi.org/10.1107/S1600536810016533
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author Anthony, Timothy A.
Arman, Hadi D.
Walmsley, Judith A.
author_facet Anthony, Timothy A.
Arman, Hadi D.
Walmsley, Judith A.
author_sort Anthony, Timothy A.
collection PubMed
description The title compound, [PdCl(2)(C(6)H(16)N(3))](C(7)H(7)SO(3)), consists of a Pd(II) atom bonded to two N atoms of the 1,4,7-triaza­cyclo­nonane (TACN) ligand and two chloride ions, which define a distorted square-planar geometry. The third N atom of the TACN ligand is protonated and hydrogen bonds to the p-toluene­sulfonate anion. The Cl—Pd—Cl angle is larger than the N—Pd—N angle. The packing is dominated by layers, which are formed by the criss-crossing of two different hydrogen-bonded chains. One chain is composed of hydrogen-bonded Pd(TACNH)Cl(2) (+) cations, while the second is formed through hydrogen bonding between the p-toluene­sulfonate anion and the Pd(TACNH)Cl(2) (+) cation.
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spelling pubmed-29795702010-12-30 Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate Anthony, Timothy A. Arman, Hadi D. Walmsley, Judith A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(6)H(16)N(3))](C(7)H(7)SO(3)), consists of a Pd(II) atom bonded to two N atoms of the 1,4,7-triaza­cyclo­nonane (TACN) ligand and two chloride ions, which define a distorted square-planar geometry. The third N atom of the TACN ligand is protonated and hydrogen bonds to the p-toluene­sulfonate anion. The Cl—Pd—Cl angle is larger than the N—Pd—N angle. The packing is dominated by layers, which are formed by the criss-crossing of two different hydrogen-bonded chains. One chain is composed of hydrogen-bonded Pd(TACNH)Cl(2) (+) cations, while the second is formed through hydrogen bonding between the p-toluene­sulfonate anion and the Pd(TACNH)Cl(2) (+) cation. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979570/ /pubmed/21579291 http://dx.doi.org/10.1107/S1600536810016533 Text en © Anthony et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Anthony, Timothy A.
Arman, Hadi D.
Walmsley, Judith A.
Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate
title Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate
title_full Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate
title_fullStr Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate
title_full_unstemmed Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate
title_short Dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) N (4),N (7))palladium(II) p-toluene­sulfonate
title_sort dichlorido(4,7-diaza-1-azoniacyclo­nonane-κ(2) n (4),n (7))palladium(ii) p-toluene­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979570/
https://www.ncbi.nlm.nih.gov/pubmed/21579291
http://dx.doi.org/10.1107/S1600536810016533
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