(E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate

In the title compound, C(25)H(22)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 32.02 (14), 37.49 (18) and 80.52 (13)°, respectively, with the pyrazolone ring, the bromo­benzene ring and the terminal phenyl ring. This conformation features a short intramolecular C—H⋯O contact that ge...

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Detalles Bibliográficos
Autores principales: Guo, Min-Jie, Chen, Xin, Yao, Jing-Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979573/
https://www.ncbi.nlm.nih.gov/pubmed/21579444
http://dx.doi.org/10.1107/S1600536810017198
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author Guo, Min-Jie
Chen, Xin
Yao, Jing-Xia
author_facet Guo, Min-Jie
Chen, Xin
Yao, Jing-Xia
author_sort Guo, Min-Jie
collection PubMed
description In the title compound, C(25)H(22)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 32.02 (14), 37.49 (18) and 80.52 (13)°, respectively, with the pyrazolone ring, the bromo­benzene ring and the terminal phenyl ring. This conformation features a short intramolecular C—H⋯O contact that generates an S(6) ring. In the crystal, inversion dimers linked by pairs of C—H⋯O=C hydrogen bonds occur.
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spelling pubmed-29795732010-12-30 (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate Guo, Min-Jie Chen, Xin Yao, Jing-Xia Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(22)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 32.02 (14), 37.49 (18) and 80.52 (13)°, respectively, with the pyrazolone ring, the bromo­benzene ring and the terminal phenyl ring. This conformation features a short intramolecular C—H⋯O contact that generates an S(6) ring. In the crystal, inversion dimers linked by pairs of C—H⋯O=C hydrogen bonds occur. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979573/ /pubmed/21579444 http://dx.doi.org/10.1107/S1600536810017198 Text en © Guo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Guo, Min-Jie
Chen, Xin
Yao, Jing-Xia
(E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate
title (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate
title_full (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate
title_fullStr (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate
title_full_unstemmed (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate
title_short (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate
title_sort (e)-5-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1h-pyrazol-4-yl)imino­meth­yl]-2-methoxy­phenyl 4-bromo­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979573/
https://www.ncbi.nlm.nih.gov/pubmed/21579444
http://dx.doi.org/10.1107/S1600536810017198
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AT chenxin e515dimethyl3oxo2phenyl23dihydro1hpyrazol4yliminomethyl2methoxyphenyl4bromobenzenesulfonate
AT yaojingxia e515dimethyl3oxo2phenyl23dihydro1hpyrazol4yliminomethyl2methoxyphenyl4bromobenzenesulfonate

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