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3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate

In the title compound, C(19)H(13)N(3)O(3)S·0.5H(2)O, both organic mol­ecules (A and B) exist in E configurations with respect to the acyclic C=N bond and have similar overall conformations. In mol­ecule A, the essentially planar thia­zole ring [maximum deviation = 0.010 (2) Å] is inclined at inter­p...

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Autores principales: Arshad, Afsheen, Osman, Hasnah, Chan, Kit Lam, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979574/
https://www.ncbi.nlm.nih.gov/pubmed/21579559
http://dx.doi.org/10.1107/S1600536810019653
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author Arshad, Afsheen
Osman, Hasnah
Chan, Kit Lam
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Arshad, Afsheen
Osman, Hasnah
Chan, Kit Lam
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Arshad, Afsheen
collection PubMed
description In the title compound, C(19)H(13)N(3)O(3)S·0.5H(2)O, both organic mol­ecules (A and B) exist in E configurations with respect to the acyclic C=N bond and have similar overall conformations. In mol­ecule A, the essentially planar thia­zole ring [maximum deviation = 0.010 (2) Å] is inclined at inter­planar angles of 11.44 (10) and 32.50 (12)°, with the 2H-chromene ring system and the benzene ring, respectively. The equivalent values for mol­ecule B are 0.002 (2) Å, 7.71 (9) and 12.51 (12)°. In the crystal structure, neighbouring mol­ecules are inter­connected into infinite layers lying parallel to (010) by O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. Further stabilization of the crystal structure is provided by weak inter­molecular C—H⋯π and π–π [centroid–centroid distance = 3.6380 (19) Å] inter­actions.
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spelling pubmed-29795742010-12-30 3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate Arshad, Afsheen Osman, Hasnah Chan, Kit Lam Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(13)N(3)O(3)S·0.5H(2)O, both organic mol­ecules (A and B) exist in E configurations with respect to the acyclic C=N bond and have similar overall conformations. In mol­ecule A, the essentially planar thia­zole ring [maximum deviation = 0.010 (2) Å] is inclined at inter­planar angles of 11.44 (10) and 32.50 (12)°, with the 2H-chromene ring system and the benzene ring, respectively. The equivalent values for mol­ecule B are 0.002 (2) Å, 7.71 (9) and 12.51 (12)°. In the crystal structure, neighbouring mol­ecules are inter­connected into infinite layers lying parallel to (010) by O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. Further stabilization of the crystal structure is provided by weak inter­molecular C—H⋯π and π–π [centroid–centroid distance = 3.6380 (19) Å] inter­actions. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979574/ /pubmed/21579559 http://dx.doi.org/10.1107/S1600536810019653 Text en © Arshad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Afsheen
Osman, Hasnah
Chan, Kit Lam
Goh, Jia Hao
Fun, Hoong-Kun
3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate
title 3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate
title_full 3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate
title_fullStr 3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate
title_full_unstemmed 3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate
title_short 3-{2-[2-(3-Hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2H-chromen-2-one hemihydrate
title_sort 3-{2-[2-(3-hy­droxy­benzyl­idene)hydrazin-1-yl]-1,3-thia­zol-4-yl}-2h-chromen-2-one hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979574/
https://www.ncbi.nlm.nih.gov/pubmed/21579559
http://dx.doi.org/10.1107/S1600536810019653
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