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3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate
In the title compound, C(19)H(13)N(3)O(3)S·0.5H(2)O, both organic molecules (A and B) exist in E configurations with respect to the acyclic C=N bond and have similar overall conformations. In molecule A, the essentially planar thiazole ring [maximum deviation = 0.010 (2) Å] is inclined at interp...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979574/ https://www.ncbi.nlm.nih.gov/pubmed/21579559 http://dx.doi.org/10.1107/S1600536810019653 |
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author | Arshad, Afsheen Osman, Hasnah Chan, Kit Lam Goh, Jia Hao Fun, Hoong-Kun |
author_facet | Arshad, Afsheen Osman, Hasnah Chan, Kit Lam Goh, Jia Hao Fun, Hoong-Kun |
author_sort | Arshad, Afsheen |
collection | PubMed |
description | In the title compound, C(19)H(13)N(3)O(3)S·0.5H(2)O, both organic molecules (A and B) exist in E configurations with respect to the acyclic C=N bond and have similar overall conformations. In molecule A, the essentially planar thiazole ring [maximum deviation = 0.010 (2) Å] is inclined at interplanar angles of 11.44 (10) and 32.50 (12)°, with the 2H-chromene ring system and the benzene ring, respectively. The equivalent values for molecule B are 0.002 (2) Å, 7.71 (9) and 12.51 (12)°. In the crystal structure, neighbouring molecules are interconnected into infinite layers lying parallel to (010) by O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. Further stabilization of the crystal structure is provided by weak intermolecular C—H⋯π and π–π [centroid–centroid distance = 3.6380 (19) Å] interactions. |
format | Text |
id | pubmed-2979574 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29795742010-12-30 3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate Arshad, Afsheen Osman, Hasnah Chan, Kit Lam Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(13)N(3)O(3)S·0.5H(2)O, both organic molecules (A and B) exist in E configurations with respect to the acyclic C=N bond and have similar overall conformations. In molecule A, the essentially planar thiazole ring [maximum deviation = 0.010 (2) Å] is inclined at interplanar angles of 11.44 (10) and 32.50 (12)°, with the 2H-chromene ring system and the benzene ring, respectively. The equivalent values for molecule B are 0.002 (2) Å, 7.71 (9) and 12.51 (12)°. In the crystal structure, neighbouring molecules are interconnected into infinite layers lying parallel to (010) by O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. Further stabilization of the crystal structure is provided by weak intermolecular C—H⋯π and π–π [centroid–centroid distance = 3.6380 (19) Å] interactions. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979574/ /pubmed/21579559 http://dx.doi.org/10.1107/S1600536810019653 Text en © Arshad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arshad, Afsheen Osman, Hasnah Chan, Kit Lam Goh, Jia Hao Fun, Hoong-Kun 3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate |
title | 3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate |
title_full | 3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate |
title_fullStr | 3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate |
title_full_unstemmed | 3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate |
title_short | 3-{2-[2-(3-Hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2H-chromen-2-one hemihydrate |
title_sort | 3-{2-[2-(3-hydroxybenzylidene)hydrazin-1-yl]-1,3-thiazol-4-yl}-2h-chromen-2-one hemihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979574/ https://www.ncbi.nlm.nih.gov/pubmed/21579559 http://dx.doi.org/10.1107/S1600536810019653 |
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